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In chemistry, a suspension is a heterogeneous mixture of a fluid that contains solid particles sufficiently large for sedimentation. The particles may be visible to the naked eye , usually must be larger than one micrometer , and will eventually settle , although the mixture is only classified as a suspension when and while the particles have ...
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
In chemistry, a mixture is a material made up of two or more different chemical substances which can be separated by physical method. It is an impure substance made up of 2 or more elements or compounds mechanically mixed together in any proportion. [ 1 ]
Some mixtures will readily form solid solutions over a range of concentrations, while other mixtures will not form solid solutions at all. The propensity for any two substances to form a solid solution is a complicated matter involving the chemical, crystallographic, and quantum properties of the substances in question.
A colloid is a heterogeneous mixture where the dispersed particles have at least in one direction a dimension roughly between 1 nm and 1 μm or that in a system discontinuities are found at distances of that order. [8] A suspension is a heterogeneous dispersion of larger particles in a medium. Unlike solutions and colloids, if left undisturbed ...
These include electrostatic interactions and van der Waals forces, because they both contribute to the overall free energy of the system. [21] A colloid is stable if the interaction energy due to attractive forces between the colloidal particles is less than kT, where k is the Boltzmann constant and T is the absolute temperature. If this is the ...
Thus, the change of the free energy in mixing is the sum of the enthalpy of mixing and the entropy of mixing. The enthalpy of mixing is zero for ideal mixtures, and ideal mixtures are enough to describe many common solutions. Thus, in many cases, mixing (or phase separation) is driven primarily by the entropy of mixing.
An ideal solution or ideal mixture is a solution that exhibits thermodynamic properties analogous to those of a mixture of ideal gases. [1] The enthalpy of mixing is zero [2] as is the volume change on mixing by definition; the closer to zero the enthalpy of mixing is, the more "ideal" the behavior of the solution becomes.
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