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The Haber process, [1] also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. [ 2 ] [ 3 ] It converts atmospheric nitrogen (N 2 ) to ammonia (NH 3 ) by a reaction with hydrogen (H 2 ) using finely divided iron metal as a catalyst:
The use of a catalyst does not affect the position and composition of the equilibrium of a reaction, because both the forward and backward reactions are sped up by the same factor. For example, consider the Haber process for the synthesis of ammonia (NH 3): N 2 + 3 H 2 ⇌ 2 NH 3
Fritz Haber, 1918. The Haber process, [5] also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. [6] [7] It converts atmospheric nitrogen (N 2) to ammonia (NH 3) by a reaction with hydrogen (H 2) using finely divided iron metal as a catalyst:
The dominant technology for abiological nitrogen fixation is the Haber process, which uses iron-based heterogeneous catalysts and H 2 to convert N 2 to NH 3. This article focuses on homogeneous (soluble) catalysts for the same or similar conversions. [1]
The history of the Haber process begins with the invention of the Haber process at the dawn of the twentieth century. The process allows the economical fixation of atmospheric dinitrogen in the form of ammonia, which in turn allows for the industrial synthesis of various explosives and nitrogen fertilizers, and is probably the most important industrial process developed during the twentieth ...
Fritz Haber, 1918. The Haber process, [146] also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. [147] [148] It converts atmospheric nitrogen (N 2) to ammonia (NH 3) by a reaction with hydrogen (H 2) using finely divided iron metal as a catalyst:
In a reversible reaction, chemical equilibrium is reached when the rates of the forward and reverse reactions are equal (the principle of dynamic equilibrium) and the concentrations of the reactants and products no longer change. This is demonstrated by, for example, the Haber–Bosch process for combining nitrogen and hydrogen to produce ammonia.
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".