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  2. Bent molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Bent_molecular_geometry

    There are several variants of bending, where the most common is AX 2 E 2 where two covalent bonds and two lone pairs of the central atom (A) form a complete 8-electron shell. They have central angles from 104° to 109.5°, where the latter is consistent with a simplistic theory which predicts the tetrahedral symmetry of four sp 3 hybridised ...

  3. Molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Molecular_geometry

    A bond angle is the geometric angle between two adjacent bonds. Some common shapes of simple molecules include: Linear: In a linear model, atoms are connected in a straight line. The bond angles are set at 180°. For example, carbon dioxide and nitric oxide have a linear molecular shape.

  4. Seesaw molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Seesaw_molecular_geometry

    An atom bonded to 5 other atoms (and no lone pairs) forms a trigonal bipyramid with two axial and three equatorial positions, but in the seesaw geometry one of the atoms is replaced by a lone pair of electrons, which is always in an equatorial position. This is true because the lone pair occupies more space near the central atom (A) than does a ...

  5. Chemical polarity - Wikipedia

    en.wikipedia.org/wiki/Chemical_polarity

    A molecule may be nonpolar either when there is an equal sharing of electrons between the two atoms of a diatomic molecule or because of the symmetrical arrangement of polar bonds in a more complex molecule. For example, boron trifluoride (BF 3) has a trigonal planar arrangement of three polar bonds at 120°. This results in no overall dipole ...

  6. Bent's rule - Wikipedia

    en.wikipedia.org/wiki/Bent's_rule

    Shape of water molecule showing that the real bond angle 104.5° deviates from the ideal sp 3 angle of 109.5°. In chemistry, Bent's rule describes and explains the relationship between the orbital hybridization and the electronegativities of substituents. [1] [2] The rule was stated by Henry A. Bent as follows: [2]

  7. Molecular symmetry - Wikipedia

    en.wikipedia.org/wiki/Molecular_symmetry

    For example, the water molecule has three normal modes of vibration: symmetric stretch in which the two O-H bond lengths vary in phase with each other, asymmetric stretch in which they vary out of phase, and bending in which the bond angle varies. The molecular symmetry of water is C 2v with four irreducible representations A 1, A 2, B 1 and B 2.

  8. Trigonal planar molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Trigonal_planar_molecular...

    Structure of boron trifluoride, an example of a molecule with trigonal planar geometry.. In chemistry, trigonal planar is a molecular geometry model with one atom at the center and three atoms at the corners of an equilateral triangle, called peripheral atoms, all in one plane. [1]

  9. Linear molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Linear_molecular_geometry

    The linear molecular geometry describes the geometry around a central atom bonded to two other atoms (or ligands) placed at a bond angle of 180°. Linear organic molecules , such as acetylene ( HC≡CH ), are often described by invoking sp orbital hybridization for their carbon centers.