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Ammonium sulfate is made by treating ammonia with sulfuric acid: 2 NH 3 + H 2 SO 4 → (NH 4) 2 SO 4. A mixture of ammonia gas and water vapor is introduced into a reactor that contains a saturated solution of ammonium sulfate and about 2% to 4% of free sulfuric acid at 60 °C.
Liquid fertilizers comprise anhydrous ammonia, aqueous solutions of ammonia, aqueous solutions of ammonium nitrate or urea. These concentrated products may be diluted with water to form a concentrated liquid fertilizer (e.g., UAN). Advantages of liquid fertilizer are its more rapid effect and easier coverage. [24]
Liquid ammonia has a very high standard enthalpy change of vapourization (23.5 kJ/mol; [28] for comparison, water's is 40.65 kJ/mol, methane 8.19 kJ/mol and phosphine 14.6 kJ/mol) and can be transported in pressurized or refrigerated vessels; however, at standard temperature and pressure liquid anhydrous ammonia will vaporize.
Ammonium nitrate is an important fertilizer with NPK rating 34-0-0 (34% nitrogen). [17] It is less concentrated than urea (46-0-0), giving ammonium nitrate a slight transportation disadvantage. Ammonium nitrate's advantage over urea is that it is more stable and does not rapidly lose nitrogen to the atmosphere.
Tiedjens also experimented with different methods of fertilizing crops. He discovered plants can absorb fertilizer nutrients only when they are in a liquid form. [4] [5] He rationalized that if he dissolved dry materials in water they would be better utilized by the plant. This led to the inception of liquid fertilizers.
Ammonia electrolysis may require much less thermodynamic energy than water electrolysis (only 0.06 V in alkaline media). [23] Another option for recovering ammonia from wastewater is to use the mechanics of the ammonia-water thermal absorption cycle. [24] [25] Ammonia can thus be recovered either as a liquid or as ammonium hydroxide. The ...
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