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Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula Al 2 O 3. It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly called alumina and may also be called aloxide, aloxite, or alundum in various forms and ...
The term "octahedral" is used somewhat loosely by chemists, focusing on the geometry of the bonds to the central atom and not considering differences among the ligands themselves. For example, [Co(NH 3) 6] 3+, which is not octahedral in the mathematical sense due to the orientation of the N−H bonds, is referred to as octahedral. [2]
Corundum is the name for a structure prototype in inorganic solids, derived from the namesake polymorph of aluminum oxide (α-Al 2 O 3). [1] Other compounds, especially among the inorganic solids, exist in corundum structure, either in ambient or other conditions.
Aluminates are often formulated as a combination of basic oxide and aluminium oxide, for example the formula of anhydrous sodium aluminate NaAlO 2 would be shown as Na 2 O·Al 2 O 3. A number of aluminate oxyanions are known: The simplest is the approximately tetrahedral AlO 5− 4 found in the compound Na 5 AlO 4, [2] framework AlO −
The spinels are any of a class of minerals of general formulation AB 2 X 4 which crystallise in the cubic (isometric) crystal system, with the X anions (typically chalcogens, like oxygen and sulfur) arranged in a cubic close-packed lattice and the cations A and B occupying some or all of the octahedral and tetrahedral sites in the lattice.
Aluminium(I) oxide (Al 2 O) Aluminium(II) oxide ( AlO ) (aluminium monoxide) Aluminium(III) oxide (aluminium oxide), ( Al 2 O 3 ), the most common form of aluminium oxide, occurring on the surface of aluminium and also in crystalline form as corundum , sapphire , and ruby .
Corundum is a crystalline form of aluminium oxide (Al 2 O 3) typically containing traces of iron, titanium, vanadium, and chromium. [3] [4] It is a rock-forming mineral.It is a naturally transparent material, but can have different colors depending on the presence of transition metal impurities in its crystalline structure. [7]
This method of cluster formation created the only known incidence of an octahedral aluminium cluster, [Al 6 (tBu) 6] −, which was formed by reaction between AlCl and t BuLi. [6] Similarly, AlCl and LiN(SiMe 3 ) 2 react to form the first known example of a cluster where two M 4 tetrahedra are connected by a common center.