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  2. Molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Molecular_geometry

    Molecules, by definition, are most often held together with covalent bonds involving single, double, and/or triple bonds, where a "bond" is a shared pair of electrons (the other method of bonding between atoms is called ionic bonding and involves a positive cation and a negative anion).

  3. Anti-periplanar - Wikipedia

    en.wikipedia.org/wiki/Anti-periplanar

    An important factor in the antiperiplanar conformer is the interaction between molecular orbitals. Anti-periplanar geometry will put a bonding orbital and an anti-bonding orbital approximately parallel to each other, or syn-periplanar.

  4. Orthogonality - Wikipedia

    en.wikipedia.org/wiki/Orthogonality

    The line segments AB and CD are perpendicular to each other. In mathematics, orthogonality is the generalization of the geometric notion of perpendicularity.Although many authors use the two terms perpendicular and orthogonal interchangeably, the term perpendicular is more specifically used for lines and planes that intersect to form a right angle, whereas orthogonal is used in generalizations ...

  5. Glossary of chemistry terms - Wikipedia

    en.wikipedia.org/wiki/Glossary_of_chemistry_terms

    Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...

  6. Cis–trans isomerism - Wikipedia

    en.wikipedia.org/wiki/Cis–trans_isomerism

    In the context of chemistry, cis indicates that the functional groups (substituents) are on the same side of some plane, while trans conveys that they are on opposing (transverse) sides. Cis – trans isomers are stereoisomers , that is, pairs of molecules which have the same formula but whose functional groups are in different orientations in ...

  7. Dihedral angle - Wikipedia

    en.wikipedia.org/wiki/Dihedral_angle

    The absolute value is required in above formulas, as the planes are not changed when changing all coefficient signs in one equation, or replacing one normal vector by its opposite. However the absolute values can be and should be avoided when considering the dihedral angle of two half planes whose boundaries are the same line.

  8. Bent's rule - Wikipedia

    en.wikipedia.org/wiki/Bent's_rule

    Both these studies show how Bent's rule can be used to aid synthetic chemistry. Knowing how molecular geometry accurately due to Bent's rule allows synthetic chemists to predict relative product stability. [14] [30] Additionally, Bent's rule can help chemists choose their starting materials to drive the reaction towards a particular product. [14]

  9. Optical rotation - Wikipedia

    en.wikipedia.org/wiki/Optical_rotation

    Dextrorotation and laevorotation (also spelled levorotation) [1] [2] in chemistry and physics are the optical rotation of plane-polarized light.From the point of view of the observer, dextrorotation refers to clockwise or right-handed rotation, and laevorotation refers to counterclockwise or left-handed rotation.