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The vanadium redox battery, a type of flow battery, is an electrochemical cell consisting of aqueous vanadium ions in different oxidation states. [ 88 ] [ 89 ] Batteries of this type were first proposed in the 1930s and developed commercially from the 1980s onwards.
Vanadium pentoxide is a commercially important catalyst for the production of sulfuric acid, a reaction that exploits the ability of vanadium oxides to undergo redox reactions. [2] The vanadium redox battery utilizes all four oxidation states: one electrode uses the +5/+4 couple and the other uses the +3/+2 couple. Conversion of these oxidation ...
Structure of vanadyl acetylacetonate Cavansite, a mineral containing the vanadyl cation that illustrates its characteristic color. The vanadyl or oxovanadium(IV) cation, VO 2+, [1] is a functional group that is common in the coordination chemistry of vanadium. Complexes containing this functional group are characteristically blue and paramagnetic.
Vanadium(II) oxide is the inorganic compound with the idealized formula VO. It is one of the several binary vanadium oxides. It adopts a distorted NaCl structure and contains weak V−V metal to metal bonds. VO is a semiconductor owing to delocalisation of electrons in the t 2g orbitals.
Relative radii of atoms and ions. The neutral atoms are colored gray, cations red, and anions blue. Ions may be larger or smaller than the neutral atom, depending on the ion's electric charge. When an atom loses an electron to form a cation, the other electrons are more attracted to the nucleus, and the radius of the ion gets smaller.
In chemistry, a vanadate is an anionic coordination complex of vanadium. Often vanadate refers to oxoanions of vanadium, most of which exist in its highest oxidation state of +5. The complexes [V(CN) 6] 3− and [V 2 Cl 9] 3− are referred to as hexacyanovanadate(III) and nonachlorodivanadate(III), respectively.
Vanadium(IV) oxide or vanadium dioxide is an inorganic compound with the formula VO 2. It is a dark blue solid. It is a dark blue solid. Vanadium (IV) dioxide is amphoteric , dissolving in non-oxidising acids to give the blue vanadyl ion , [VO] 2+ and in alkali to give the brown [V 4 O 9 ] 2− ion, or at high pH [VO 4 ] 4− . [ 4 ]
The vanadium redox battery (VRB), also known as the vanadium flow battery (VFB) or vanadium redox flow battery (VRFB), is a type of rechargeable flow battery. It employs vanadium ions as charge carriers . [ 6 ]