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The terms "intensive and extensive quantities" were introduced into physics by German mathematician Georg Helm in 1898, and by American physicist and chemist Richard C. Tolman in 1917. [ 1 ] [ 2 ] According to International Union of Pure and Applied Chemistry (IUPAC), an intensive property or intensive quantity is one whose magnitude is ...
The intensive (force) variable is the derivative of the internal energy with respect to the extensive (displacement) variable, while all other extensive variables are held constant. The thermodynamic square can be used as a tool to recall and derive some of the thermodynamic potentials based on conjugate variables.
They are called intensive variables or extensive variables according to how they change when the size of the system changes. The properties of the system can be described by an equation of state which specifies the relationship between these variables. State may be thought of as the instantaneous quantitative description of a system with a set ...
In thermodynamics, a physical property is any property that is measurable, and whose value describes a state of a physical system. Thermodynamic properties are defined as characteristic features of a system, capable of specifying the system's state.
Enthalpy is an extensive property; it is proportional to the size of the system (for homogeneous systems). As intensive properties, the specific enthalpy h = H/m is referenced to a unit of mass m of the system, and the molar enthalpy H m = H/n, where n is the number of moles.
Extensive parameters are properties of the entire system, as contrasted with intensive parameters which can be defined at a single point, such as temperature and pressure. The extensive parameters (except entropy) are generally conserved in some way as long as the system is "insulated" to changes to that parameter from the outside. The truth of ...
This allows the definition of an intensive state variable, with respect to a reference state of the surroundings, for that substance. The intensive variable is called the chemical potential; for component substance i it is usually denoted μ i. The corresponding extensive variable can be the number of moles N i of the component substance in the ...
An intensive property does not depend on the size or extent of the system, nor on the amount of matter in the object, while an extensive property shows an additive relationship. These classifications are in general only valid in cases when smaller subdivisions of the sample do not interact in some physical or chemical process when combined.