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Ethyl acrylate reacts with amines catalyzed by Lewis acids in a Michael addition to β-alanine derivatives in high yields: [13]. The nucleophilic addition at ethyl acrylate as an α,β-unsaturated carbonyl compound is a frequent strategy in the synthesis of pharmaceutical intermediates.
Hazardous chemicals present physical and/or health threats to workers in clinical, industrial, and academic laboratories. Laboratory chemicals include cancer-causing agents (carcinogens), toxins (e.g., those affecting the liver, kidney, and nervous system), irritants, corrosives, sensitizers, as well as agents that act on the blood system or damage the lungs, skin, eyes, or mucous membranes.
2-Ethylhexyl acrylate is a colorless liquid acrylate used in the making of paints, [2] plastics [3] and adhesives. [4] It has an odor that has been variously described as pleasant [ 5 ] or acrid and musty.
When ethyl acrylate is used as a reactant, ethanol is formed; this forms with the ethyl acrylate an azeotrope of the composition ethanol/ethyl acrylate 72.7:26.3%, which boils at 77.5 °C under atmospheric pressure. [8] To achieve a high reaction yield, the ethanol is distilled off from the reaction mixture.
The acrylate ion is the anion CH 2 =CHCO − 2. Often, acrylate refers to esters of acrylic acid, the most common member being methyl acrylate. These acrylates contain vinyl groups. These compounds are of interest because they are bifunctional: the vinyl group is susceptible to polymerization and the carboxylate group carries myriad ...
Chemical structure of ethyl cyanoacrylate, the precursor to many commercial adhesives. The most common monomer is ethyl cyanoacrylate.Several related esters are known. To facilitate easy handling, a cyanoacrylate monomer is frequently formulated with an ingredient such as fumed silica to make it more viscous or gel-like.
The term immediately dangerous to life or health (IDLH) is defined by the US National Institute for Occupational Safety and Health (NIOSH) as exposure to airborne contaminants that is "likely to cause death or immediate or delayed permanent adverse health effects or prevent escape from such an environment." Examples include smoke or other ...
Ethyl acrylate was once used as synthetic food flavoring and was withdrawn by FDA possibly due to cancerogenic effects observed in lab animals. [13] Animal studies showed that high-doses of acrylic acid decreased weight gain. Acrylic acid can be converted to non-toxic lactic acid. [14] Acrylic acid is a constituent of tobacco smoke. [15]