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Potassium iodide is a chemical compound, ... The oxidation of iodide causes slow loss of iodine content from iodised salts that are exposed to excess air.
This clock reaction uses sodium, potassium or ammonium persulfate to oxidize iodide ions to iodine. Sodium thiosulfate is used to reduce iodine back to iodide before the iodine can complex with the starch to form the characteristic blue-black color. Iodine is generated: 2 I − + S 2 O 2− 8 → I 2 + 2 SO 2− 4. And is then removed:
Hypervalent iodine oxyanions are known for oxidation states +1, +3, +5, and +7; organic analogues of these moieties are known for each oxidation state except +7. In terms of chemical behavior, λ 3 ‑ and λ 5 ‑iodanes are generally oxidizing and/or electrophilic species. They have been widely applied towards those ends in organic synthesis. [1]
(Nonetheless, nitrogen triiodide is named as an iodide as it is analogous to the other nitrogen trihalides.) [7] Given the large size of the iodide anion and iodine's weak oxidising power, high oxidation states are difficult to achieve in binary iodides, the maximum known being in the pentaiodides of niobium, tantalum, and protactinium. Iodides ...
For prolonged titrations, it is advised to add dry ice to the titration mixture to displace air from the Erlenmeyer flask so as to prevent the aerial oxidation of iodide to iodine. Standard iodine solution is prepared from potassium iodate and potassium iodide, which are both primary standards: IO − 3 + 8 I − + 6 H + → 3 I − 3 + 3 H 2 O
If ozonolysis is performed by introducing a stream of ozone-enriched oxygen through the reaction mixture, the effluent gas can be directed through a potassium iodide solution. When the solution has stopped absorbing ozone, the excess ozone oxidizes the iodide to iodine, which can easily be observed by its violet color. [6]
Percentage of share of households consuming iodized salt. Edible salt can be iodised by spraying it with a potassium iodate or potassium iodide solution. 57 grams of potassium iodate, costing about US$1.15 (in 2006), is required to iodise a ton (2,000 pounds) of salt. [1]
An iodide ion is I −. [2] Compounds with iodine in formal oxidation state −1 are called iodides.In everyday life, iodide is most commonly encountered as a component of iodized salt, which many governments mandate.