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Most of the ozone production occurs in the tropical upper stratosphere and mesosphere. The total mass of ozone produced per day over the globe is about 400 million metric tons. The global mass of ozone is relatively constant at about 3 billion metric tons, meaning the Sun produces about 12% of the ozone layer each day. [1]
It has been determined that the ozone decomposition follows a first order kinetics, and from the rate law above it can be determined that the partial order respect to molecular oxygen is -1 and respect to ozone is 2, therefore the global reaction order is 1. The ozone decomposition consists of two elementary steps: The first one corresponds to ...
Ground-level ozone (O 3), also known as surface-level ozone and tropospheric ozone, is a trace gas in the troposphere (the lowest level of the Earth's atmosphere), with an average concentration of 20–30 parts per billion by volume (ppbv), with close to 100 ppbv in polluted areas.
The symbol M represents a "third body", an unspecified molecular species that must interact with the reactants in order to carry away energy from the exothermic reaction. The 3 P designation on the atomic O species is the term symbol for its electronic state, indicating that it is in a spin triplet state , which is the ground electronic state ...
Ozone in the troposhere is determined by photochemical production and destruction, dry deposition and cross-tropopause transport of ozone from the stratosphere. [2] In the Arctic troposphere, transport and photochemical reactions involving nitrogen oxides and volatile organic compounds (VOCs) as a result of human emissions also produce ozone resulting in a background mixing ratio of 30 to 50 ...
At current rates of primary production, today's concentration of oxygen could be produced by photosynthetic organisms in 2,000 years. [4] In the absence of plants, the rate of oxygen production by photosynthesis was slower in the Precambrian, and the concentrations of O 2 attained were less than 10% of today's and probably fluctuated greatly.
Ozone-oxygen cycle in the ozone layer. The photochemical mechanisms that give rise to the ozone layer were discovered by the British physicist Sydney Chapman in 1930. Ozone in the Earth's stratosphere is created by ultraviolet light striking ordinary oxygen molecules containing two oxygen atoms (O 2), splitting them into individual oxygen atoms (atomic oxygen); the atomic oxygen then combines ...
While there are many abiotic sources and sinks for O 2, the presence of the profuse concentration of free oxygen in modern Earth's atmosphere and ocean is attributed to O 2 production from the biological process of oxygenic photosynthesis in conjunction with a biological sink known as the biological pump and a geologic process of carbon burial involving plate tectonics.