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The Maxwell–Boltzmann distribution applies fundamentally to particle velocities in three dimensions, but turns out to depend only on the speed (the magnitude of the velocity) of the particles. A particle speed probability distribution indicates which speeds are more likely: a randomly chosen particle will have a speed selected randomly from ...
In other words, the configuration of particle A in state 1 and particle B in state 2 is different from the case in which particle B is in state 1 and particle A is in state 2. This assumption leads to the proper (Boltzmann) statistics of particles in the energy states, but yields non-physical results for the entropy, as embodied in the Gibbs ...
Particle velocity (denoted v or SVL) is the velocity of a particle (real or imagined) in a medium as it transmits a wave. The SI unit of particle velocity is the metre per second (m/s). In many cases this is a longitudinal wave of pressure as with sound , but it can also be a transverse wave as with the vibration of a taut string.
A free particle with mass in non-relativistic quantum mechanics is described by the free Schrödinger equation: (,) = (,) where ψ is the wavefunction of the particle at position r and time t . The solution for a particle with momentum p or wave vector k , at angular frequency ω or energy E , is given by a complex plane wave :
= where is the relaxation time of the particle (the time constant in the exponential decay of the particle velocity due to drag), is the fluid velocity of the flow well away from the obstacle, and is the characteristic dimension of the obstacle (typically its diameter) or a characteristic length scale in the flow (like boundary layer thickness ...
Boltzmann's distribution is an exponential distribution. Boltzmann factor (vertical axis) as a function of temperature T for several energy differences ε i − ε j.. In statistical mechanics and mathematics, a Boltzmann distribution (also called Gibbs distribution [1]) is a probability distribution or probability measure that gives the probability that a system will be in a certain ...
Thus, indirectly, thermal velocity is a measure of temperature. Technically speaking, it is a measure of the width of the peak in the Maxwell–Boltzmann particle velocity distribution . Note that in the strictest sense thermal velocity is not a velocity , since velocity usually describes a vector rather than simply a scalar speed .
This dependence on microscopic variables is the central point of statistical mechanics. With a model of the microscopic constituents of a system, one can calculate the microstate energies, and thus the partition function, which will then allow us to calculate all the other thermodynamic properties of the system.