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Molar volume. In chemistry and related fields, the molar volume, symbol Vm, [1] or of a substance is the ratio of the volume (V) occupied by a substance to the amount of substance (n), usually at a given temperature and pressure. It is also equal to the molar mass (M) divided by the mass density (ρ): The molar volume has the SI unit of cubic ...
Molar concentration (also called molarity, amount concentration or substance concentration) is a measure of the concentration of a chemical species, in particular, of a solute in a solution, in terms of amount of substance per unit volume of solution. In chemistry, the most commonly used unit for molarity is the number of moles per liter ...
Volume fraction. In chemistry and fluid mechanics, the volume fraction is defined as the volume of a constituent Vi divided by the volume of all constituents of the mixture V prior to mixing: [1] Being dimensionless, its unit is 1; it is expressed as a number, e.g., 0.18. It is the same concept as volume percent (vol%) except that the latter is ...
Specific volume. In thermodynamics, the specific volume of a substance (symbol: ν, nu) is the quotient of the substance's volume (V) to its mass (m): It is a mass-specific intrinsic property of the substance. It is the reciprocal of density ρ (rho) and it is also related to the molar volume and molar mass: The standard unit of specific volume ...
Cubic equations of state. Cubic equations of state are a specific class of thermodynamic models for modeling the pressure of a gas as a function of temperature and density and which can be rewritten as a cubic function of the molar volume. Equations of state are generally applied in the fields of physical chemistry and chemical engineering ...
The van der Waals equation, named for its originator, the Dutch physicist Johannes Diderik van der Waals, is an equation of state that extends the ideal gas law to include the non-zero size of gas molecules and the interactions between them (both of which depend on the specific substance). As a result the equation is able to model the phase ...
Apparent molar property. In thermodynamics, an apparent molar property of a solution component in a mixture or solution is a quantity defined with the purpose of isolating the contribution of each component to the non-ideality of the mixture. It shows the change in the corresponding solution property (for example, volume) per mole of that ...
The molar volume of gases around STP and at atmospheric pressure can be calculated with an accuracy that is usually sufficient by using the ideal gas law. The molar volume of any ideal gas may be calculated at various standard reference conditions as shown below: V m = 8.3145 × 273.15 / 101.325 = 22.414 dm 3 /mol at 0 °C and 101.325 kPa