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Inside the cracks, the water evaporates and the amount of hydroxide keeps increasing progressively. The concentrated area with high stress works as anode and diluted area works as cathode. At anode, sodium hydroxide attacks the surrounding material and then dissolves the iron of the boiler as sodium ferrate forming rust.
A study of the influence of chloride ion concentration on the corrosion behavior of carbon steel in phosphate high-temperature boiler water chemistries. Anti-Corrosion Methods and Materials, 55(1), 15–19. Sendelbach, M. (1988). Boiler-water treatment: Why, what and how. Chemical Engineering, 95(11), 127. Characteristics of boiler feed water ...
The reduction of blowdown by dealkalization keeps the water treatment chemicals in the boiler longer, thus minimizing the amount of chemicals required for efficient, noncorrosive operation. [2] Carbonate and bicarbonate alkalinities are decomposed by heat in boiler water releasing carbon dioxide into the steam.
Excessive conductivity values often indicate high corrosion potential, especially with certain ions such as chloride and acetate ions. These can be particularly damaging to the blades in the steam turbine. Degas conductivity is measured after the water sample has flowed through a resin and has had carbon dioxide removed by a degassing process ...
Steam and water analysis system (SWAS) [1] is a system dedicated to the analysis of steam or water.In power stations, it is usually used to analyze boiler steam and water to ensure the water used to generate electricity is clean from impurities which can cause corrosion to any metallic surface, such as in boiler and turbine.
With oxygenated treatment, oxygen is injected into the feedwater to keep the oxygen level between 30 and 50 ppb. OT programs are most commonly used in supercritical (i.e. >3250psi) power boilers. The ability to change an existing sub-critical boiler over to an OT program is very limited.
Boiler water treatment is a type of industrial water treatment focused on the removal or chemical modification of substances potentially damaging to the boiler. Varying types of treatment are used at different locations to avoid scale, corrosion, or foaming. [3] External treatment of raw water supplies intended for use within a boiler is ...
The next step is to add dilute stannous chloride reagent, which has been freshly prepared from concentrated stannous chloride reagent and distilled water, to the mixture in the tube. This will produce a blue colour (due to the formation of molybdenum blue ) and the depth of the blue colour indicates the amount of phosphate in the boiler water.