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A dielectric permittivity spectrum over a wide range of frequencies. ε′ and ε″ denote the real and the imaginary part of the permittivity, respectively. Various processes are labeled on the image: ionic and dipolar relaxation, and atomic and electronic resonances at higher energies. [9]
A dielectric permittivity spectrum over a wide range of frequencies. The real and imaginary parts of permittivity are shown, and various processes are depicted: ionic and dipolar relaxation, and atomic and electronic resonances at higher energies.
According to classical physics, the speed of light varies with the permittivity of a material: = where is the velocity of light through the material, is the material permittivity, and is the material permeability. Because the permittivity is anisotropic, polarized light of different orientations will travel at different speeds.
The relative permittivity of a medium is related to its electric susceptibility, χ e, as ε r (ω) = 1 + χ e. In anisotropic media (such as non cubic crystals) the relative permittivity is a second rank tensor. The relative permittivity of a material for a frequency of zero is known as its static relative permittivity.
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The simplest way to approach the problem is to treat each material as a homogeneous continuum, described by a frequency-dependent relative permittivity between the external medium and the surface. This quantity, hereafter referred to as the materials' "dielectric function", is the complex permittivity.
An alternative description of the response to alternating currents uses a real (but frequency-dependent) conductivity, along with a real permittivity. The larger the conductivity is, the more quickly the alternating-current signal is absorbed by the material (i.e., the more opaque the material is).
The real (blue solid line) and imaginary (orange dashed line) components of relative permittivity are plotted for model with parameters = 3.2 eV, = 4.5 eV, = 100 eV, = 1 eV, and = 3.5. The Tauc–Lorentz model is a mathematical formula for the frequency dependence of the complex-valued relative permittivity , sometimes referred to as the ...