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The general structure of an organic peroxide. In organic chemistry, organic peroxides are organic compounds containing the peroxide functional group (R−O−O−R′).If the R′ is hydrogen, the compounds are called hydroperoxides, which are discussed in that article.
Benzoyl peroxide is a chemical compound (specifically, an organic peroxide) with structural formula (C 6 H 5 −C(=O)O−) 2, often abbreviated as (BzO) 2.In terms of its structure, the molecule can be described as two benzoyl (C 6 H 5 −C(=O)−, Bz) groups connected by a peroxide (−O−O−).
The O-O σ bond in dibenzoyl peroxide is cleaved homolytically, distributing a radical to each benzoyloxy. Heat Certain intramolecular bonds, such as the O–O bond of a peroxide, are sufficiently weak to spontaneously homolytically dissociate near room temperature. Most bonds homolyse at temperatures above 200°C. [4]
In addition to hydrogen peroxide, some other major classes of peroxides are: Peroxy acids, the peroxy derivatives of many familiar acids, examples being peroxymonosulfuric acid and peracetic acid, and their salts, one example of which is potassium peroxydisulfate. Main group peroxides, compounds with the linkage E−O−O−E (E = main group ...
Acid rain can have harmful effects on plants, aquatic animals, and infrastructure. Acid rain is caused by emissions of sulfur dioxide and nitrogen oxide, which react with the water molecules in the atmosphere to produce acids. Acid rain has been shown to have adverse impacts on forests, freshwaters, soils, microbes, insects and aquatic life ...
The example shown here consists of indenylzirconium (a metallocene) and benzoyl peroxide (an initiator). Also, initiating systems containing heteroaromatic diketo carboxylic acids, such as 3,6-bis( o -carboxybenzoyl)- N -isopropylcarbazole in this example, are known to catalyze the decomposition of benzoyl peroxide.
Autoxidation is therefore a fairly broad term and can encompass examples of photooxygenation and catalytic oxidation. The common mechanism is a free radical chain reaction, where the addition of oxygen gives rise to hydroperoxides and their associated peroxy radicals (ROO•). [5]
In many cases, the resin is provided as a solution or mixture with a thermally-activated catalyst, which induces crosslinking but only upon heating. For example, some acrylate-based resins are formulated with dibenzoyl peroxide. Upon heating the mixture, the peroxide converts to a free radical, which adds to an acrylate, initiating crosslinking.