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J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
Enthalpies of melting and boiling for pure elements versus temperatures of transition, demonstrating Trouton's rule. In thermodynamics, the enthalpy of fusion of a substance, also known as (latent) heat of fusion, is the change in its enthalpy resulting from providing energy, typically heat, to a specific quantity of the substance to change its state from a solid to a liquid, at constant pressure.
Latent heat is energy released or absorbed by a body or a thermodynamic system during a constant-temperature process. Two common forms of latent heat are latent heat of fusion and latent heat of vaporization . These names describe the direction of energy flow when changing from one phase to the next: from solid to liquid, and liquid to gas.
In some texts, the heats of phase transitions are called latent heats (for example, latent heat of fusion). Molar enthalpy of zinc above 298.15 K and at 1 atm pressure, showing discontinuities at the melting and boiling points. The ΔH°m of zinc is 7323 J/mol, and the ΔH°v is 115 330 J/mol.
J.A. Dean (ed.), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
of fusion, Δ fus H o +4.9 kJ/mol Std entropy change of fusion, Δ fus S o +31 J/(mol·K) Std enthalpy change of vaporization, Δ vap H o +42.3 ± 0.4 kJ/mol [4] Std entropy change of vaporization, Δ vap S o: 109.67 J/(mol·K) Molal freezing point constant: −1.99 °C kg/mol Solid properties Std enthalpy change of formation, Δ f H o solid ...
Heat capacity, c p [2] 96 J/(mol K) Liquid properties Std enthalpy change of formation, Δ f H o liquid: −249.4 kJ/mol Standard molar entropy, S o liquid: 200.4 J/(mol K) Enthalpy of combustion, Δ c H o –1785.7 kJ/mol Heat capacity, c p: 125.5 J/(mol K) Gas properties Std enthalpy change of formation, Δ f H o gas: −218.5 kJ/mol Standard ...
Standard enthalpy change of fusion, Δ fus H o: 9.9 kJ/mol Standard entropy change of fusion, Δ fus S o: 38.2 J/(mol·K) Standard enthalpy change of vaporization, Δ vap H o: 65.6 kJ/mol Standard entropy change of vaporization, Δ vap S o? J/(mol·K) Solid properties Standard enthalpy change of formation, Δ f H o solid? kJ/mol Standard molar ...