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In 1890, Rydberg proposed on a formula describing the relation between the wavelengths in spectral lines of alkali metals. [2]: v1:376 He noticed that lines came in series and he found that he could simplify his calculations using the wavenumber (the number of waves occupying the unit length, equal to 1/λ, the inverse of the wavelength) as his unit of measurement.
where ν is the frequency of the wave, λ is the wavelength, ω = 2πν is the angular frequency of the wave, and v p is the phase velocity of the wave. The dependence of the wavenumber on the frequency (or more commonly the frequency on the wavenumber) is known as a dispersion relation.
The phase velocity is the rate at which the phase of the wave propagates in space. The group velocity is the rate at which the wave envelope, i.e. the changes in amplitude, propagates. The wave envelope is the profile of the wave amplitudes; all transverse displacements are bound by the envelope profile.
Wave speed is a wave property, which may refer to absolute value of: phase velocity , the velocity at which a wave phase propagates at a certain frequency group velocity , the propagation velocity for the envelope of wave groups and often of wave energy, different from the phase velocity for dispersive waves
Rules for wavelength of maximum diene absorption [3] [7] With the aid of these rules the UV absorption maximum can be predicted, for example in these two compounds: [ 8 ] In the compound on the left, the base value is 214 nm (a heteroannular diene).
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
The electromagnetic wave equation is a second-order partial differential equation that describes the propagation of electromagnetic waves through a medium or in a vacuum. It is a three-dimensional form of the wave equation. The homogeneous form of the equation, written in terms of either the electric field E or the magnetic field B, takes the form:
A wave packet has an envelope that describes the overall amplitude of the wave; within the envelope, the distance between adjacent peaks or troughs is sometimes called a local wavelength. [21] [22] An example is shown in the figure. In general, the envelope of the wave packet moves at a speed different from the constituent waves. [23]