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  2. Conjugated system - Wikipedia

    en.wikipedia.org/wiki/Conjugated_system

    Cinnamaldehyde is a naturally-occurring compound that has a conjugated system penta-1,3-diene is a molecule with a conjugated system Diazomethane conjugated pi-system. In theoretical chemistry, a conjugated system is a system of connected p-orbitals with delocalized electrons in a molecule, which in general lowers the overall energy of the molecule and increases stability.

  3. Topological conjugacy - Wikipedia

    en.wikipedia.org/wiki/Topological_conjugacy

    In mathematics, two functions are said to be topologically conjugate if there exists a homeomorphism that will conjugate the one into the other. Topological conjugacy, and related-but-distinct § Topological equivalence of flows, are important in the study of iterated functions and more generally dynamical systems, since, if the dynamics of one iterative function can be determined, then that ...

  4. Homoconjugation - Wikipedia

    en.wikipedia.org/wiki/Homoconjugation

    In organic chemistry, homoconjugation is a type of conjugated system where two π-systems are separated by one non-conjugating group. See Conjugated system#Mechanism . Topics referred to by the same term

  5. Antarafacial and suprafacial - Wikipedia

    en.wikipedia.org/wiki/Antarafacial_and_suprafacial

    The reaction center can be a p-or sp n-orbital (Woodward-Hoffmann symbol ω), a conjugated system (π) or even a sigma bond (σ). The relationship is antarafacial when opposite faces of the π system or isolated orbital are involved in the process (think anti). For a σ bond, it corresponds to involvement of one "interior" lobe and one ...

  6. Diels–Alder reaction - Wikipedia

    en.wikipedia.org/wiki/Diels–Alder_reaction

    (The same conclusion can be drawn from an orbital correlation diagram or a Dewar-Zimmerman analysis.) For the more common "normal" electron demand Diels–Alder reaction, the more important of the two HOMO/LUMO interactions is that between the electron-rich diene's ψ 2 as the highest occupied molecular orbital (HOMO) with the electron ...

  7. Porphyrin - Wikipedia

    en.wikipedia.org/wiki/Porphyrin

    [2] [3] One result of the large conjugated system is that porphyrins typically absorb strongly in the visible region of the electromagnetic spectrum, i.e. they are deeply colored. The name "porphyrin" derives from Greek πορφύρα (porphyra) 'purple'.

  8. Double bond - Wikipedia

    en.wikipedia.org/wiki/Double_bond

    In molecules with alternating double bonds and single bonds, p-orbital overlap can exist over multiple atoms in a chain, giving rise to a conjugated system. Conjugation can be found in systems such as dienes and enones. In cyclic molecules, conjugation can lead to aromaticity. In cumulenes, two double bonds are adjacent.

  9. Electrocyclic reaction - Wikipedia

    en.wikipedia.org/wiki/Electrocyclic_reaction

    These correlation diagrams indicate that only a conrotatory ring opening of 3,4-dimethylcyclobutene is symmetry allowed whereas only a disrotatory ring opening of 5,6-dimethylcyclohexa-1,3-diene is symmetry allowed. This is because only in these cases would maximum orbital overlap occur in the transition state. Also, the formed product would be ...

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