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The class of "constitutive relations" of the form stress rate = f (velocity gradient, stress, density) was the subject of Walter Noll's dissertation in 1954 under Clifford Truesdell. [2] In modern condensed matter physics, the constitutive equation plays a major role. See Linear constitutive equations and Nonlinear correlation functions. [3]
In continuum physics, materials with memory, also referred as materials with hereditary effects are a class of materials whose constitutive equations contains a dependence upon the past history of thermodynamic, kinetic, electromagnetic or other kind of state variables.
In engineering, physics, and chemistry, the study of transport phenomena concerns the exchange of mass, energy, charge, momentum and angular momentum between observed and studied systems. While it draws from fields as diverse as continuum mechanics and thermodynamics , it places a heavy emphasis on the commonalities between the topics covered.
The properties are better studied using tensor-valued constitutive equations, which are common in the field of continuum mechanics. For non-Newtonian fluid's viscosity, there are pseudoplastic, plastic, and dilatant flows that are time-independent, and there are thixotropic and rheopectic flows that are time-dependent.
In physics, there are equations in every field to relate physical quantities to each other and perform calculations. Entire handbooks of equations can only summarize most of the full subject, else are highly specialized within a certain field. Physics is derived of formulae only.
The concept of a continuum underlies the mathematical framework for studying large-scale forces and deformations in materials. Although materials are composed of discrete atoms and molecules, separated by empty space or microscopic cracks and crystallographic defects, physical phenomena can often be modeled by considering a substance distributed throughout some region of space.
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For this case only two components of the shear stress became non-zero: = ˙ and = ˙ where ˙ is the shear rate.. Thus, the upper-convected Maxwell model predicts for the simple shear that shear stress to be proportional to the shear rate and the first difference of normal stresses is proportional to the square of the shear rate, the second difference of normal stresses is always zero.