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The heat capacity is a function of the amount of heat added to a system. In the case of a constant-volume process, all the heat affects the internal energy of the system (i.e., there is no pV-work, and all the heat affects the temperature).
The volumetric heat capacity of a material is the heat capacity of a sample of the substance divided by the volume of the sample. It is the amount of energy that must be added, in the form of heat , to one unit of volume of the material in order to cause an increase of one unit in its temperature .
The injection of heat energy into a substance, besides raising its temperature, usually causes an increase in its volume and/or its pressure, depending on how the sample is confined. The choice made about the latter affects the measured specific heat capacity, even for the same starting pressure p {\displaystyle p} and starting temperature T ...
For example, Paraffin has very large molecules and thus a high heat capacity per mole, but as a substance it does not have remarkable heat capacity in terms of volume, mass, or atom-mol (which is just 1.41 R per mole of atoms, or less than half of most solids, in terms of heat capacity per atom).
This creates a limit to the amount of heat energy that can do work in a cyclic process, a limit called the available energy. Mechanical and other forms of energy can be transformed in the other direction into thermal energy without such limitations. [14] The total energy of a system can be calculated by adding up all forms of energy in the system.
The energy content (high or low heating value) of a volume of natural gas varies with the composition of the natural gas, which means there is no universal conversion factor for energy to volume. 1 cubic foot (28 litres) of average natural gas yields ≈ 1,030 Btu (between 1,010 Btu and 1,070 Btu, depending on quality, when burned)
The molar heat capacity is the heat capacity per unit amount (SI unit: mole) of a pure substance, and the specific heat capacity, often called simply specific heat, is the heat capacity per unit mass of a material. Heat capacity is a physical property of a substance, which means that it depends on the state and properties of the substance under ...
GCSE Bitesize was launched in January 1998, covering seven subjects. For each subject, a one- or two-hour long TV programme would be broadcast overnight in the BBC Learning Zone block, and supporting material was available in books and on the BBC website. At the time, only around 9% of UK households had access to the internet at home.