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This Wikipedia page provides a comprehensive list of boiling and freezing points for various solvents.
A comparison of S N 1 to S N 2 reactions is to the right. On the left is an S N 1 reaction coordinate diagram. Note the decrease in ΔG ‡ activation for the polar-solvent reaction conditions. This arises from the fact that polar solvents stabilize the formation of the carbocation intermediate to a greater extent than the non-polar-solvent ...
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
The hydride surface can also be functionalized with carboxylic acids [2] and long-chain alkyl groups. [2] Mobile phases for ANPC are based on organic solvents as bulk solvents (such as methanol or acetonitrile) with a small amount of water as a modifier of polarity; thus, the mobile phase is both "aqueous" (water is present) and "normal phase ...
log 10 of Acetonitrile vapor pressure. ... Vapor-liquid Equilibrium for Acetonitrile/Methanol [4] P = 760 mmHg BP Temp. °C % by mole methanol liquid vapor 79.20: 2.5:
CH 3 CO 2 H: acetic acid: 64-19-7 (CH 3) 2 CO: acetone: 67-64-1 CH 3 CN: acetonitrile: 75-05-8 CH 3 CH 2 CH(OH)CH 2 OH: 1,2-Butanediol: 584-03-2 CH 3 CH(OH)CH 2 CH 2 OH: 1,3-Butanediol: 107-88-0 HOCH 2 CH 2 CH 2 CH 2 OH: 1,4-Butanediol: 110-63-4 C 6 H 14 O 2: 2-Butoxyethanol: 111-76-2 CH 3 CH 2 CH 2 COOH: butyric acid: 107-92-6 HN(CH 2 CH 2 OH ...
Acetonitrile is used mainly as a solvent in the purification of butadiene in refineries. Specifically, acetonitrile is fed into the top of a distillation column filled with hydrocarbons including butadiene, and as the acetonitrile falls down through the column, it absorbs the butadiene which is then sent from the bottom of the tower to a second separating tower.
A polar aprotic solvent is a solvent that lacks an acidic proton and is polar. Such solvents lack hydroxyl and amine groups. In contrast to protic solvents , these solvents do not serve as proton donors in hydrogen bonding , although they can be proton acceptors.
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