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The structures of solid magnesium citrates have been characterized by X-ray crystallography.In the 1:1 salt, only one carboxylate of citrate is deprotonated. It has the formula Mg(H 2 C 6 H 5 O 7) 2 The other form of magnesium citrate has the formula Mg(HC 6 H 5 O 7)(H 2 O) 2, consisting of the citrate dianion (both carboxylic acids are deprotonated). [1]
The anhydrous salt has good solubilty in water (~10% or more at 25°C) and contains 16.2% elemental magnesium by weight. Its taste is slightly bitter-alkaline. The hydrated salt may have 3 to 14 molecules of water attached to it and has much lower solubility in water (2% or less at 25°C). [1] This form doesn't have any noticeable taste.
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Magnesium is absorbed orally at about 30% bioavailability from any water soluble salt, such as magnesium chloride or magnesium citrate. The citrate is the least expensive soluble (high bioavailability) oral magnesium salt available in supplements, with 100 mg and 200 mg magnesium typically contained per capsule, tablet or 50 mg/mL in solution. [26]
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