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Hydroamination has been utilized to synthesize the allylamine Cinnarizine in quantitative yield. Cinnarizine treats both vertigo and motion sickness related nausea. [26] Synthesis of cinnarizine via hydroamination. Hydroamination is also promising for the synthesis of alkaloids. An example was the hydroamination step used in the total synthesis ...
In hydroamination, amines add to alkenes. [3] When substituted amines add, the result is alkene carboamination. See also. Alkylation, the addition of an alkyl group;
In organic chemistry, a coupling reaction is a type of reaction in which two reactant molecules are bonded together. Such reactions often require the aid of a metal catalyst.
An alkaline hydrolysis disposal system at the Biosecurity Research Institute inside of Pat Roberts Hall at Kansas State University. Alkaline hydrolysis (also called biocremation, resomation, [1] [2] flameless cremation, [3] aquamation [4] or water cremation [5]) is a process for the disposal of human and pet remains using lye and heat; it is alternative to burial, cremation, or sky burial.
Neutral alanes are not nucleophilic enough to deliver organic groups to electrophilic substrates. However, upon activation by a nucleophile, the resulting aluminates are highly nucleophilic and add to electrophiles with retention of configuration at the migration carbon.
Apart from finding new catalysts for the hydroamination of alkenes and alkynes, Müller has also determined the X-ray crystal structure of the transition-metal catalyst [PdCl(triphos)](CF 3 SO 3) that is active for the intramolecular hydroamination of alkynes [11] and developed novel reaction systems for hydroamination reactions, such as a ...
The Cope reaction or Cope elimination, developed by Arthur C. Cope, is the elimination reaction of an N-oxide to an alkene and a hydroxylamine. [1] [2] [3] [4]Cope reaction ...
hydroamination; hydroalkoxylation; olefin polymerization; which are crucial in promoting efficient synthesis of complex molecules as the products of these reactions often serve as key intermediates or building blocks in further transformations. [5]