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Printable version; Page information; Get shortened URL; Download QR code; In other projects Appearance. ... Di-tert-butyl ether chemical structure: Date: 22 April 2007:
Print/export Download as PDF; Printable version; In other projects Wikimedia Commons; Wikidata item; Appearance. ... Di-tert-butyl ether is a tertiary ether, ...
Print/export Download as PDF; Printable version; In other projects Wikidata item; ... Di-n-propyl ether; Di-tert-butyl ether; Dibutyl ether; Diethyl ether; Diglycidyl ...
Print/export Download as PDF; Printable version; In other projects Wikimedia Commons; ... Di-tert-butyl ether; Di(propylene glycol) methyl ether; Dibutyl ether;
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
Each HHB of the tert-butyl network were calculated (in absence of steric repulsion) to contribute 0.7 kcal/mol of stabilization. Calculations with one of the tert-butyl substituents with a methyl, ethyl, or isopropyl group result in net repulsion due to the loss of HHBs. [26] In total, this forms the basis of the corset effect. [5]
Printable version; In other projects Wikidata item; ... 3,3-Di-tert-butyl-2,2,4,4-tetramethylpentane; Heptadecane This page was last edited on 2 May 2021, at 18:22 ...
One example of a moderately stable thiosulfinate is the tert-butyl derivative, (CH 3) 3 CS(O)SC(CH 3) 3. This thiosulfinate can be obtained in optical purity by catalytic asymmetric oxidation of di-tert-butyl disulfide with hydrogen peroxide. [17]