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Printable version; Page information; Get shortened URL; Download QR code; In other projects Appearance. ... Di-tert-butyl ether chemical structure: Date: 22 April 2007:
Printable version; In other projects Wikimedia Commons; Wikidata item; Appearance. move to sidebar hide ... Di-tert-butyl ether is a tertiary ether, ...
Printable version; In other projects ... Di-tert-butyl ether; Di(propylene glycol) methyl ether ... Methyl tert-butyl ether; 2-Methyltetrahydrofuran; Morpholine; P ...
The addition of tri-tert-butyl cyclopropenium ion produces the thermally stable cyclopropenyl phosphine intermediate. Upon irradiation with 254 nm light in the presence of triflic acid and either tetra- n -butyl ammonium chloride or tetramethylammonium fluoride , the anthracene leaving group is forced out, leaving a halogenated phosphine.
Printable version; In other projects Wikidata item; Appearance. move to sidebar hide. Help ... Di-n-propyl ether; Di-tert-butyl ether; Dibutyl ether; Diethyl ether;
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
One example of a moderately stable thiosulfinate is the tert-butyl derivative, (CH 3) 3 CS(O)SC(CH 3) 3. This thiosulfinate can be obtained in optical purity by catalytic asymmetric oxidation of di-tert-butyl disulfide with hydrogen peroxide. [17]
The tert-butoxide is a strong, non-nucleophilic base in organic chemistry. It readily abstracts acidic protons from substrates, but its steric bulk inhibits the group from participating in nucleophilic substitution, such as in a Williamson ether synthesis or an S N 2 reaction. tert-Butyl alcohol reacts with hydrogen chloride to form tert-butyl ...
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