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As typically measured, one kcal/mol represents a temperature increase of one degree Celsius in one liter of water (with a mass of 1 kg) resulting from the reaction of one mole of reagents. In SI units, one kilocalorie per mole is equal to 4.184 kilojoules per mole (kJ/mol), which comes to approximately 6.9477 × 10 −21 joules per molecule, or ...
For example, Paraffin has very large molecules and thus a high heat capacity per mole, but as a substance it does not have remarkable heat capacity in terms of volume, mass, or atom-mol (which is just 1.41 R per mole of atoms, or less than half of most solids, in terms of heat capacity per atom).
All values refer to 25 °C and to the thermodynamically stable standard state at that temperature unless noted. Values from CRC refer to "100 kPa (1 bar or 0.987 standard atmospheres)".
The SI unit of molar heat capacity is joule per kelvin per mole, J⋅K −1 ⋅mol −1. Like the specific heat, the measured molar heat capacity of a substance, especially a gas, may be significantly higher when the sample is allowed to expand as it is heated ( at constant pressure , or isobaric ) than when it is heated in a closed vessel that ...
For example, terrestrial air is primarily made up of diatomic gases (around 78% nitrogen, N 2, and 21% oxygen, O 2), and at standard conditions it can be considered to be an ideal gas. The above value of 1.4 is highly consistent with the measured adiabatic indices for dry air within a temperature range of 0–200 °C, exhibiting a deviation of ...
[1] For a fuel of composition C c H h O o N n, the (higher) heat of combustion is 419 kJ/mol × (c + 0.3 h − 0.5 o) usually to a good approximation (±3%), [2] [3] though it gives poor results for some compounds such as (gaseous) formaldehyde and carbon monoxide, and can be significantly off if o + n > c, such as for glycerine dinitrate, C 3 ...
For a gas, it is the hypothetical state the gas would assume if it obeyed the ideal gas equation at a pressure of 1 bar. For a gaseous or solid solute present in a diluted ideal solution , the standard state is the hypothetical state of concentration of the solute of exactly one mole per liter (1 M ) at a pressure of 1 bar extrapolated from ...
The specific heat capacities of iron, granite, and hydrogen gas are about 449 J⋅kg −1 ⋅K −1, 790 J⋅kg −1 ⋅K −1, and 14300 J⋅kg −1 ⋅K −1, respectively. [4] While the substance is undergoing a phase transition , such as melting or boiling, its specific heat capacity is technically undefined, because the heat goes into ...