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Mixture of polymers and solvent on a lattice. Flory–Huggins solution theory is a lattice model of the thermodynamics of polymer solutions which takes account of the great dissimilarity in molecular sizes in adapting the usual expression for the entropy of mixing. The result is an equation for the Gibbs free energy change for mixing a polymer ...
Viscosity models for mixtures. The shear viscosity (or viscosity, in short) of a fluid is a material property that describes the friction between internal neighboring fluid surfaces (or sheets) flowing with different fluid velocities. This friction is the effect of (linear) momentum exchange caused by molecules with sufficient energy to move ...
The diluted material must be thoroughly mixed to achieve the true dilution. For example, in a solution with a 1:5 dilution ratio, entails combining 1 unit volume of solute (the material to be diluted) with 5 unit volumes of the solvent to give 6 total units of total volume. In photographic development, dilutions are normally given in a '1+x ...
The Debye–Hückel theory was proposed by Peter Debye and Erich Hückel as a theoretical explanation for departures from ideality in solutions of electrolytes and plasmas. [1] It is a linearized Poisson–Boltzmann model, which assumes an extremely simplified model of electrolyte solution but nevertheless gave accurate predictions of mean activity coefficients for ions in dilute solution.
Solution (chemistry) Making a saline water solution by dissolving table salt (NaCl) in water. The salt is the solute and the water the solvent. In chemistry, a solution is a special type of homogeneous mixture composed of two or more substances. In such a mixture, a solute is a substance dissolved in another substance, known as a solvent.
The lowest value is when the mole fraction is 0.5 for a mixture of two components, or 1/n for a mixture of n components. The entropy of mixing for an ideal solution of two species is maximized when the mole fraction of each species is 0.5.
Volume fraction. In chemistry and fluid mechanics, the volume fraction is defined as the volume of a constituent Vi divided by the volume of all constituents of the mixture V prior to mixing: [1] Being dimensionless, its unit is 1; it is expressed as a number, e.g., 0.18. It is the same concept as volume percent (vol%) except that the latter is ...
Mass fraction (chemistry) In chemistry, the mass fraction of a substance within a mixture is the ratio (alternatively denoted ) of the mass of that substance to the total mass of the mixture. [1] Expressed as a formula, the mass fraction is: Because the individual masses of the ingredients of a mixture sum to , their mass fractions sum to unity: