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Related to the preparation of Lucas' reagent, tetrachlorozincates are often generated by combining hydrochloric acid and zinc chloride. A related anion is [Zn 2 Cl 6] 2−, in which again Zn(II) adopts a tetrahedral geometry. [2] Portion of the crystal structure of the salt hexaacetonitrilenickel(II) tetrachlorozincate ([Ni(CH 3 CN) 6] 2+ [ZnCl ...
Zinc pyrithione (or pyrithione zinc) is a coordination complex of zinc. It has fungistatic (inhibiting the division of fungal cells) and bacteriostatic (inhibiting bacterial cell division) properties and is used in the treatment of seborrhoeic dermatitis [ 2 ] and dandruff .
Zinc may be classified as a post-transition main group element with zinc(II). Zinc compounds are noteworthy for their nondescript appearance and behavior: they are generally colorless (unlike compounds of other elements with oxidation number +2, which are colored), do not readily engage in redox reactions, and generally adopt symmetrical ...
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Zinc is refined by froth flotation of the ore, roasting, and final extraction using electricity (electrowinning). Zinc is an essential trace element for humans, [8] [9] [10] animals, [11] plants [12] and for microorganisms [13] and is necessary for prenatal and postnatal development. [14]
The compound crystallizes in a tetragonal body-centered unit cell of space group symmetry I4 1 md. In the solid-state diethylzinc shows nearly linear Zn centres. The Zn-C bonds measure 194.8(5) pm, while the C-Zn-C angle is slightly bent with 176.2(4)°. [6]
Zinc complexes merit inclusion in the Irving-Williams series as zinc forms many complexes with the same stoichiometry as complexes of copper(II), albeit with smaller stability constants. [25] There is little similarity between cadmium and silver as compounds of silver(II) are rare and those that do exist are very strong oxidizing agents.
Like most other perchlorates such as copper perchlorate and lead perchlorate, zinc perchlorate is prone to deliquescence. Zinc perchlorate can form complexes with ligands such as 8-aminoquinoline , tricarbohydrazide, and tetraphenylethylene tetratriazole.