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Hydrogen peroxide (H 2 O 2) can be used as HOCl scavenger whose byproducts do not interfere in the Pinnick oxidation reaction: HOCl + H 2 O 2 → HCl + O 2 + H 2 O. In a weakly acidic condition, fairly concentrated (35%) H 2 O 2 solution undergoes a rapid oxidative reaction with no competitive reduction reaction of HClO 2 to form HOCl. HClO 2 ...
Hydrogen peroxide is a chemical compound with the formula H 2 O 2.In its pure form, it is a very pale blue [5] liquid that is slightly more viscous than water.It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3%–6% by weight) in water for consumer use and in higher concentrations for industrial use.
The hypochlorite anion and chlorine are in equilibrium in water; the position of the equilibrium is pH dependent and low pH (acidic) favors chlorine, [11] Cl 2 + H 2 O ⇌ 2H + + Cl − + ClO −. A hypochlorite bleach can react violently with hydrogen peroxide and produce oxygen gas: H 2 O 2 (aq) + NaOCl (aq) → NaCl (aq) + H 2 O(l) + O 2 (g)
The rate of ozone generation is influenced by the conditions of the electrolysis reactor. Sustained reactions are capable of generating a solution saturated in ozone, though the solubility of ozone depends on the concentration of other ions. [8] In the next stage, with little change in reaction conditions, hydrogen peroxide is produced.
Common oxidizing agents are oxygen, hydrogen peroxide, and the halogens. In one sense, an oxidizing agent is a chemical species that undergoes a chemical reaction in which it gains one or more electrons. In that sense, it is one component in an oxidation–reduction (redox) reaction. In the second sense, an oxidizing agent is a chemical species ...
Oxidizing bleaching agents that do not contain chlorine are usually based on peroxides, such as hydrogen peroxide, sodium percarbonate, and sodium perborate. These bleaches are called "non-chlorine bleach", "oxygen bleach", or "color-safe bleach". [2]
In the Kornblum–DeLaMare rearrangement, a peroxide is converted to a ketone and an alcohol. The disproportionation of hydrogen peroxide into water and oxygen catalysed by either potassium iodide or the enzyme catalase: 2 H 2 O 2 → 2 H 2 O + O 2. In the Boudouard reaction, carbon monoxide disproportionates to carbon and carbon dioxide.
Hypochlorite salts formed by the reaction between chlorine and alkali and alkaline earth metal hydroxides. The reaction is performed at close to room temperature to suppress the formation of chlorates. This process is widely used for the industrial production of sodium hypochlorite (NaClO) and calcium hypochlorite (Ca(ClO) 2).