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Alcohol by volume (abbreviated as alc/vol or ABV) is a standard measure of the volume of alcohol contained in a given volume of an alcoholic beverage, expressed as a volume percent. [ 1 ] [ 2 ] [ 3 ] It is defined as the number of millilitres (mL) of pure ethanol present in 100 mL (3.5 imp fl oz; 3.4 US fl oz) of solution at 20 °C (68 °F).
The volume of such a mixture is slightly less than the sum of the volumes of the components. Thus, by the above definition, the term "40% alcohol by volume" refers to a mixture of 40 volume units of ethanol with enough water to make a final volume of 100 units, rather than a mixture of 40 units of ethanol with 60 units of water.
Excess volume of the mixture of ethanol and water (volume contraction) Heat of mixing of the mixture of ethanol and water Vapor–liquid equilibrium of the mixture of ethanol and water (including azeotrope) Solid–liquid equilibrium of the mixture of ethanol and water (including eutecticum) Miscibility gap in the mixture of dodecane and ethanol
The concentration of alcohol in a beverage is usually stated as the percentage of alcohol by volume (ABV, the number of milliliters (ml) of pure ethanol in 100 ml of beverage) or as proof. In the United States, proof is twice the percentage of alcohol by volume at 60 degrees Fahrenheit (e.g. 80 proof = 40% ABV).
Ethanol-water mixtures have less volume than the sum of their individual components at the given fractions. Mixing equal volumes of ethanol and water results in only 1.92 volumes of mixture. [75] [80] Mixing ethanol and water is exothermic, with up to 777 J/mol [81] being released at 298 K. Hydrogen bonding in solid ethanol at −186 °C
High percentage ethanol mixtures are used in some racing engine applications as the very high octane rating of ethanol is compatible with very high compression ratios. Ethanol fuel mixtures have "E" numbers which describe the percentage of ethanol fuel in the mixture by volume, for example, E85 is 85% anhydrous ethanol and 15% gasoline. Low ...
The proof system in the United States was established around 1848 and was based on percent alcohol rather than specific gravity. Fifty percent alcohol by volume was defined as 100 proof. [4] This is different from 50% volume fraction (expressed as a percentage); the latter does not take into account change in volume on mixing, whereas the ...
Anhydrous ethanol can be blended with gasoline (petrol) for use in gasoline engines, but with high ethanol content only after engine modifications to meter increased fuel volume since pure ethanol contains only 2/3 the energy of an equivalent volume of pure gasoline. High percentage ethanol mixtures are used in some racing engine applications ...