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Chromate conversion coating or alodine coating is a type of conversion coating used to passivate steel, aluminium, zinc, cadmium, copper, silver, titanium, magnesium, and tin alloys. [ 1 ] : p.1265 [ 2 ] The coating serves as a corrosion inhibitor , as a primer to improve the adherence of paints and adhesives , [ 2 ] as a decorative finish, or ...
A conversion coating is a chemical or electro-chemical treatment applied to manufactured parts that superficially converts the material into a thin adhering coating of an insoluble compound. These coatings are commonly applied to protect the part against corrosion , to improve the adherence of other coatings, for lubrication , or for aesthetic ...
The Cronak process is a conventional chromate conversion coating process developed in 1933 by The New Jersey Zinc Company. [1] It involves immersing a zinc or zinc-plated article for 5 to 15 seconds in a chromate solution, typically prepared from sodium dichromate and sulfuric acid. [2]
It is relevant to chromate conversion coating, which is used to passivate common metal alloys such as aluminium, zinc, cadmium, copper, silver, magnesium, and tin. [2] In conversion coating chromate reacts with these metals to prevent corrosion, retain electrical conductivity, and provide a finish for the appearance of the final alloy products. [3]
Zinc chromate, Zn Cr O 4, is a chemical compound, a salt containing the chromate anion, appearing as odorless yellow powder or yellow-green crystals, but, when used for coatings, pigments are often added. [2] [3] [4] It is used industrially in chromate conversion coatings, having been developed by the Ford Motor Company in the 1920s. [5]
Aluminium chromate conversion coatings are amorphous in structure with a gel-like composition hydrated with water. [18] Chromate conversion is a common way of passivating not only aluminium, but also zinc, cadmium, copper, silver, magnesium, and tin alloys. Anodizing is an electrolytic process that forms a thicker oxide layer.
Coatings of moderate thickness 1.8 μm to 25 μm (0.00007" to 0.001") [16] are known as Type II in North America, as named by MIL-A-8625, while coatings thicker than 25 μm (0.001") are known as Type III, hard-coat, hard anodizing, or engineered anodizing. Very thin coatings similar to those produced by chromic anodizing are known as Type IIB.
Hexavalent chromium plating solution is used for both decorative and hard plating, as well as bright dipping of copper alloys, chromic acid anodizing, and chromate conversion coating. [2] A typical hexavalent chromium plating process is: Activation bath; Chromium bath; Rinse; Second rinse
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