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Electrochemistry. English chemist John Daniell (left) and physicist Michael Faraday (right), both credited as founders of electrochemistry. Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference and identifiable chemical change. These reactions involve electrons moving via an ...
Standard electrode potential (data page) The data below tabulates standard electrode potentials (E °), in volts relative to the standard hydrogen electrode (SHE), at: Temperature 298.15 K (25.00 °C; 77.00 °F); Effective concentration (activity) 1 mol/L for each aqueous or amalgamated (mercury-alloyed) species; Unit activity for each solvent ...
Charge transfer coefficient. Charge transfer coefficient, and symmetry factor (symbols α and β, respectively) are two related parameters used in description of the kinetics of electrochemical reactions. They appear in the Butler–Volmer equation and related expressions. The symmetry factor and the charge transfer coefficient are ...
Standard hydrogen electrode. In electrochemistry, the standard hydrogen electrode (abbreviated SHE), is a redox electrode which forms the basis of the thermodynamic scale of oxidation-reduction potentials. Its absolute electrode potential is estimated to be 4.44 ± 0.02 V[ 1 ] at 25 °C, but to form a basis for comparison with all other ...
Randles–Sevcik equation. In electrochemistry, the Randles–Ševčík equation describes the effect of scan rate on the peak current (ip) for a cyclic voltammetry experiment. For simple redox events where the reaction is electrochemically reversible, and the products and reactants are both soluble, such as the ferrocene / ferrocenium couple ...
An electric battery is a source of electric power consisting of one or more electrochemical cells with external connections [ 1 ] for powering electrical devices. When a battery is supplying power, its positive terminal is the cathode and its negative terminal is the anode. [ 2 ] The terminal marked negative is the source of electrons that will ...
A reference electrode is an electrode that has a stable and well-known electrode potential. The overall chemical reaction taking place in a cell is made up of two independent half-reactions, which describe chemical changes at the two electrodes. To focus on the reaction at the working electrode, the reference electrode is standardized with ...
The electrochemical mechanisms of electrocatalytic processes are a common research subject for various fields of chemistry and associated sciences. This is important to the development of water oxidation and fuel cells catalysts. For example, half the water oxidation reaction is the reduction of protons to hydrogen, the subsequent half reaction.