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In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula −OH and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry , alcohols and carboxylic acids contain one or more hydroxy groups.
The hydroxyl radical can damage virtually all types of macromolecules: carbohydrates, nucleic acids , lipids (lipid peroxidation) and amino acids (e.g. conversion of Phe to m-Tyrosine and o-Tyrosine). The hydroxyl radical has a very short in vivo half-life of approximately 10 −9 seconds and a high reactivity. [5]
A branch of physics that studies atoms as isolated systems of electrons and an atomic nucleus. Compare nuclear physics. atomic structure atomic weight (A) The sum total of protons (or electrons) and neutrons within an atom. audio frequency A periodic vibration whose frequency is in the band audible to the average human, the human hearing range.
Structure of the hydroxyl (-OH) functional group. The suffix –ol is used in organic chemistry principally to form names of organic compounds containing the hydroxyl (–OH) group, mainly alcohols. The suffix was extracted from the word alcohol. The suffix also appears in some trivial names with reference to oils (from Latin oleum, oil).
h 2 o 2 → 2 •oh Ultimately, both reactions generate hydroxyl radicals. These radicals are oxidative in nature and nonselective with a redox potential of E 0 = +3.06 V. [ 24 ] This is significantly greater than many common organic compounds, which typically are not greater than E 0 = +2.00 V. [ 25 ] This results in the non-selective ...
By definition, a telechelic polymer is a di-end-functional polymer where both ends possess the same functionality. [2] Where the chain-ends of the polymer are not of the same functionality they are termed di-end-functional polymers. All polymers resulting from living polymerization are end-functional but may not necessarily be telechelic. [2]
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mechanics, analytical dynamics and chemical equilibria.
2R 3 C−H + O 2 → 2 R 3 C−OH R 3 C−H + O 2 + 2e − + 2H + → R 3 C−OH + H 2 O. Since O 2 itself is a slow and unselective hydroxylating agent, catalysts are required to accelerate the pace of the process and to introduce selectivity. [1] Hydroxylation is often the first step in the degradation of organic compounds in air.