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Nickel nitrate is the inorganic compound Ni(NO 3) 2 or any hydrate thereof. In the hexahydrate, the nitrate anions are not bonded to nickel. Other hydrates have also been reported: Ni(NO 3) 2. 9H 2 O, Ni(NO 3) 2. 4H 2 O, and Ni(NO 3) 2. 2H 2 O. [3] It is prepared by the reaction of nickel oxide with nitric acid: NiO + 2 HNO 3 + 5 H 2 O → Ni ...
In the NO − 3 anion, the oxidation state of the central nitrogen atom is V (+5). This corresponds to the highest possible oxidation number of nitrogen. Nitrate is a potentially powerful oxidizer as evidenced by its explosive behaviour at high temperature when it is detonated in ammonium nitrate (NH 4 NO 3), or black powder, ignited by the shock wave of a primary explosive.
Nitrogen trioxide or nitrate radical is an oxide of nitrogen with formula NO 3, consisting of three oxygen atoms covalently bound to a nitrogen atom. This highly unstable blue compound has not been isolated in pure form, but can be generated and observed as a short-lived component of gas, liquid, or solid systems. [1] Like nitrogen dioxide NO
2 HNO 3 ⇌ H 2 NO + 3 + NO − 3 ⇌ H 2 O + [NO 2] + + [NO 3] −. Two hydrates, HNO 3 ·H 2 O and HNO 3 ·3H 2 O, are known that can be crystallised. It is a strong acid and concentrated solutions are strong oxidising agents, though gold, platinum, rhodium, and iridium are immune to attack.
N 2 O 4 undergoes molecular autoionization to give [NO +] [NO 3 −], with the former nitrosonium ion being a strong oxidant. The method is illustrated by the route to β-Cu(NO 3) 2: Cu + 2 N 2 O 4 → Cu(NO 3) 2 + 2 NO. Many metals, metal halides, and metal carbonyls undergo similar reactions, but the product formulas can be deceptive.
The preferred nitrogen electron acceptors in order of most to least thermodynamically favorable include nitrate (NO 3 −), nitrite (NO 2 −), nitric oxide (NO), nitrous oxide (N 2 O) finally resulting in the production of dinitrogen (N 2) completing the nitrogen cycle.
Due to relatively weak N–O bonding, all nitrogen oxides are unstable with respect to N 2 and O 2, which is the principle behind the catalytic converter, and prevents the oxygen and nitrogen in the atmosphere from combusting.
Nickel hydrazine nitrate (NHN), (chemical formula: [Ni(N 2 H 4) 3](NO 3) 2 is an energetic material having explosive properties in between that of primary explosive and a secondary explosive. [1] It is a salt of a coordination compound of nickel with a reaction equation of 3N 2 H 4 ·H 2 O + Ni(NO 3) 2 →〔Ni(N 2 H 4) 3 〕(NO 3) 2 + 3H 2 O [2]