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Sodium perchlorate is the precursor to ammonium, potassium and lithium perchlorate salts, often taking advantage of their low solubility in water relative to NaClO 4 (209 g/(100 mL) at 25 °C). [ 6 ] It is used for denaturating proteins in biochemistry and in standard DNA extraction and hybridization reactions in molecular biology .
Perchlorate salts are typically manufactured through the process of electrolysis, which involves oxidizing aqueous solutions of corresponding chlorates.This technique is commonly employed in the production of sodium perchlorate, which finds widespread use as a key ingredient in rocket fuel. [5]
Sodium perchlorate – NaClO 4; Sodium periodate – NaIO 4; Sodium permanganate – NaMnO 4; Sodium peroxide – Na 2 O 2; Sodium peroxycarbonate – Na 2 CO 4; Sodium perrhenate – NaReO 4; Sodium persulfate – Na 2 S 2 O 8; Sodium phosphate; see trisodium phosphate – Na 3 PO 4; Sodium selenate – Na 2 O 4 Se; Sodium selenide – Na 2 Se ...
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Ammonium perchlorate (AP) is produced by reaction between ammonia and perchloric acid. This process is the main outlet for the industrial production of perchloric acid . The salt also can be produced by salt metathesis reaction of ammonium salts with sodium perchlorate .
Sodium chlorate is an inorganic compound with the chemical formula Na ClO 3.It is a white crystalline powder that is readily soluble in water. It is hygroscopic.It decomposes above 300 °C to release oxygen [4] and leaves sodium chloride.
Anhydrous perchlorate complexes are susceptible to hydrolysis: Cu(ClO 4) 2 + 6 H 2 O → [Cu(H 2 O) 6](ClO 4) 2. Upon heating, perchlorate complexes yield oxides, evolving chlorine oxides in the process. For example, thermolysis of titanium perchlorate gives TiO 2, ClO 2, and O 2 The titanyl species TiO(ClO 4) 2 is an intermediate in this ...
Hydronium perchlorate is produced by the reaction of anhydrous perchloric acid and water in a 1:1 molar ratio: [2]. HClO 4 + H 2 O → [H 3 O] + ClO − 4. A more analytically reliable method was reported using the macrocyclic Schiff base of sodium 2,6-diformyl-4-methylphenolate and 2,6-diformyl-4-methylphenol as a chelating agent to sequester Cu(II): transmetallation of the macrocycle with ...