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Gadolinium as a metal or a salt absorbs neutrons and is, therefore, used sometimes for shielding in neutron radiography and in nuclear reactors. Like most of the rare earths, gadolinium forms trivalent ions with fluorescent properties, and salts of gadolinium(III) are used as phosphors in various applications.
Nanoparticles of gadolinium oxide is a potential contrast agent for magnetic resonance imaging (MRI). A dextran-coated preparation of 20–40 nm sized gadolinium oxide particles had a relaxivity of 4.8 s −1 mM −1 per gadolinium ion at 7.05 T (an unusually high field compared to the clinically used MRI scanners which mostly range from 0.5 to ...
Gadolinium isotopes have 10 metastable isomers, with the most stable being 143m Gd (t 1/2 = 110 seconds), 145m Gd (t 1/2 = 85 seconds) and 141m Gd (t 1/2 = 24.5 seconds). The primary decay mode at atomic weights lower than the most abundant stable isotope, 158 Gd, is electron capture , and the primary mode at higher atomic weights is beta decay .
Gadolinium monosulfide forms crystals of cubic system, space group Fm4m, unit cell parameter a = 0.5574 nm, Z = 4, isomorphous with NaCl. [ 4 ] [ 5 ] GdS melts congruently at 2300 °C.
Gadolinium(III) nitride can be prepared by the direct reaction of gadolinium metal and nitrogen gas at 1600 °C and at a pressure of 1300 atm. [4] 2Gd + N 2 → 2GdN Properties
The decahydrate of gadolinium oxalate thermally decomposes to obtain the anhydrous form, which can then be heated to produce gadolinium oxide. [2] Gadolinium oxalate reacts with hydrochloric acid to produce Gd(C 2 O 4)Cl. [3] It also reacts with sodium hydroxide under hydrothermal conditions to produce gadolinium hydroxide. [1]
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