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Use of homochiral as a synonym is strongly discouraged. [22] A chiral substance is enantioenriched or heterochiral when its enantiomeric ratio is greater than 50:50 but less than 100:0. [23] Enantiomeric excess or e.e. is the difference between how much of one enantiomer is present compared to the other.
For all intents and purposes, each enantiomer in a pair has the same energy. However, theoretical physics predicts that due to parity violation of the weak nuclear force (the only force in nature that can "tell left from right"), there is actually a minute difference in energy between enantiomers (on the order of 10 −12 eV or 10 −10 kJ/mol ...
The energy that a physical body possesses due to its motion, defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. The body continues to maintain this kinetic energy unless its velocity changes. Contrast potential energy. Kirchhoff's circuit laws. Also called Kirchhoff's rules or simply Kirchhoff's laws.
In organic chemistry, enols are a type of functional group or intermediate in organic chemistry containing a group with the formula C=C(OH) (R = many substituents). The term enol is an abbreviation of alkenol, a portmanteau deriving from "-ene"/"alkene" and the "-ol".
For unsymmetrical products, the more substituted alkenes (those with fewer hydrogens attached to the C=C) tend to predominate (see Zaitsev's rule). Two common methods of elimination reactions are dehydrohalogenation of alkyl halides and dehydration of alcohols.
Very often, cis–trans stereoisomers contain double bonds or ring structures. In both cases the rotation of bonds is restricted or prevented. [4] When the substituent groups are oriented in the same direction, the diastereomer is referred to as cis, whereas when the substituents are oriented in opposing directions, the diastereomer is referred to as trans.
3 orbitals of low energy: d xy, d xz and d yz and; 2 orbitals of high energy: d z 2 and d x 2 −y 2. The energy difference between these 2 sets of d-orbitals is called the splitting parameter, Δ o. The magnitude of Δ o is determined by the field-strength of the ligand: strong field ligands, by definition, increase Δ o more than weak field ...
General structure of 1,2-, 1,3-, and 1,4-dicarbonyls. In organic chemistry, a dicarbonyl is a molecule containing two carbonyl (C=O) groups.Although this term could refer to any organic compound containing two carbonyl groups, it is used more specifically to describe molecules in which both carbonyls are in close enough proximity that their reactivity is changed, such as 1,2-, 1,3-, and 1,4 ...