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A buffer solution is a solution where the pH does not change significantly on dilution or if an acid or base is added at constant temperature. [1] Its pH changes very little when a small amount of strong acid or base is added to it. Buffer solutions are used as a means of keeping pH at a nearly constant value in a wide variety of chemical ...
A buffer solution contains an acid and its conjugate base or a base and its conjugate acid. [2] Addition of the conjugate ion will result in a change of pH of the buffer solution. For example, if both sodium acetate and acetic acid are dissolved in the same solution they both dissociate and ionize to produce acetate ions .
A simple buffer solution consists of a solution of an acid and a salt of the conjugate base of the acid. For example, the acid may be acetic acid and the salt may be sodium acetate . The Henderson–Hasselbalch equation relates the pH of a solution containing a mixture of the two components to the acid dissociation constant , K a of the acid ...
The condition to get a partially ideal solution on mixing is that the volume of the resulting mixture V to equal double the volume V s of each solution mixed in equal volumes due to the additivity of volumes. The resulting volume can be found from the mass balance equation involving densities of the mixed and resulting solutions and equalising ...
Microscopic here implies that quantum mechanics has to be used to provide an accurate description of the system. Many can be anywhere from three to infinity (in the case of a practically infinite, homogeneous or periodic system, such as a crystal), although three- and four-body systems can be treated by specific means (respectively the Faddeev and Faddeev–Yakubovsky equations) and are thus ...
Flory–Huggins solution theory is a lattice model of the thermodynamics of polymer solutions which takes account of the great dissimilarity in molecular sizes in adapting the usual expression for the entropy of mixing.
A metal-ion buffer provides a controlled source of free metal ions in a manner similar to the regulation of hydrogen ion concentration by a pH buffer [1] A metal-ion buffer solution contains the free (hydrated) metal ion along with a complex compound formed by the association of the ion with a ligand in excess.
The following is a list of notable unsolved problems grouped into broad areas of physics. [1] Some of the major unsolved problems in physics are theoretical, meaning that existing theories seem incapable of explaining a certain observed phenomenon or experimental result.