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In thermodynamics, Trouton's rule states that the (molar) entropy of vaporization has almost the same value, about 85–88 J/(K·mol), for various kinds of liquids at their boiling points. [1] The entropy of vaporization is defined as the ratio between the enthalpy of vaporization and the boiling temperature. It is named after Frederick Thomas ...
In thermodynamics, the chemical potential of a species is the energy that can be absorbed or released due to a change of the particle number of the given species, ...
In classical thermodynamics, the entropy of a system is defined if and only if it is in a thermodynamic equilibrium (though a chemical equilibrium is not required: for example, the entropy of a mixture of two moles of hydrogen and one mole of oxygen in standard conditions is well-defined).
[5] Chemical reactions, as macroscopic unit operations, consist of simply a very large number of elementary reactions, where a single molecule reacts with another molecule. As the reacting molecules (or moieties) consist of a definite set of atoms in an integer ratio, the ratio between reactants in a complete reaction is also in integer ratio.
In thermodynamics, the entropy of mixing is the increase in the total entropy when several initially separate systems of different composition, each in a thermodynamic state of internal equilibrium, are mixed without chemical reaction by the thermodynamic operation of removal of impermeable partition(s) between them, followed by a time for establishment of a new thermodynamic state of internal ...
In physics and engineering, heat flux or thermal flux, sometimes also referred to as heat flux density [1], heat-flow density or heat-flow rate intensity, is a flow of energy per unit area per unit time. Its SI units are watts per square metre (W/m 2). It has both a direction and a magnitude, and so it is a vector quantity.
The hazards of ammonia solutions depend on the concentration: 'dilute' ammonia solutions are usually 5–10% by weight (< 5.62 mol/L); 'concentrated' solutions are usually prepared at >25% by weight. A 25% (by weight) solution has a density of 0.907 g/cm 3 , and a solution that has a lower density will be more concentrated.
A benchmark material to this end is MOF-177 which was found to store hydrogen at 7.5 wt % with a volumetric capacity of 32 g L −1 at 77 K and 70 bar. [130] MOF-177 consists of [Zn 4 O] 6+ clusters interconnected by 1,3,5-benzenetribenzoate organic linkers and has a measured BET surface area of 4630 m 2 g −1.