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Iron-carbon phase diagram. α-Iron is a fairly soft metal that can dissolve only a small concentration of carbon (no more than 0.021% by mass at 910 °C). [133] Austenite (γ-iron) is similarly soft and metallic but can dissolve considerably more carbon (as much as 2.04% by mass at 1146 °C).
Steel is between 0 and 2.06 mass percent of carbon. Cast iron is between 2.06 and 6.67%. Black lines indicate the metastable Fe/Fe3Cphase, red is the stable Fe/Carbon phase This diagram is for illustrative purposes only, and is not thermodynamically accurate.
Low-pressure phase diagram of pure iron. BCC is body centered cubic and FCC is face-centered cubic. Iron-carbon eutectic phase diagram, showing various forms of Fe x C y substances. Iron allotropes, showing the differences in structure. The alpha iron (α-Fe) is a body-centered cubic (BCC) and the gamma iron (γ-Fe) is a face-centered cubic (FCC).
This exothermic reaction is used in the iron and steel industry to smelt iron and to control the carbon content of steel: Fe 3 O 4 + 4 C (s) + 2 O 2 → 3 Fe (s) + 4 CO 2 (g). Carbon reacts with sulfur to form carbon disulfide, and it reacts with steam in the coal-gas reaction used in coal gasification: C (s) + H 2 O (g) → CO (g) + H 2(g).
Iron has five nitrides observed at ambient conditions, Fe 2 N, Fe 3 N 4, Fe 4 N, Fe 7 N 3 and Fe 16 N 2.They are crystalline, metallic solids. Group 7 and group 8 transition metals form nitrides that decompose at relatively low temperatures—iron nitride, Fe 2 N decomposes with loss of molecular nitrogen at around 400 °C and formation of lower-nitrogen content iron nitrides.
Crystal structure of iron(II) oxalate dihydrate, showing iron (gray), oxygen (red), carbon (black), and hydrogen (white) atoms. Blood-red positive thiocyanate test for iron(III) Iron(III) complexes are quite similar to those of chromium(III) with the exception of iron(III)'s preference for O-donor instead of N-donor ligands. The latter tend to ...
Free nitrogen atoms easily react with most elements to form nitrides, and even when two free nitrogen atoms collide to produce an excited N 2 molecule, they may release so much energy on collision with even such stable molecules as carbon dioxide and water to cause homolytic fission into radicals such as CO and O or OH and H. Atomic nitrogen is ...
The exact atomicity of metals, as well as some other elements such as carbon, cannot be determined because they consist of a large and indefinite number of atoms bonded together. They are typically designated as having an atomicity of 2. The atomicity of homonuclear molecule can be derived by dividing the molecular weight by the atomic weight.