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  2. Polyhedral skeletal electron pair theory - Wikipedia

    en.wikipedia.org/wiki/Polyhedral_skeletal...

    In chemistry the polyhedral skeletal electron pair theory (PSEPT) provides electron counting rules useful for predicting the structures of clusters such as borane and carborane clusters. The electron counting rules were originally formulated by Kenneth Wade , [ 1 ] and were further developed by others including Michael Mingos ; [ 2 ] they are ...

  3. Zintl phase - Wikipedia

    en.wikipedia.org/wiki/Zintl_phase

    The geometry and bonding of a Zintl ion cannot be easily described by classical two electron two center bonding theories; however the geometries Zintl ions can be well described by Wade’s rules of boranes. Wade’s rules offer an alternative model for the relationship between geometry and electron count in delocalized electron deficient ...

  4. Isolobal principle - Wikipedia

    en.wikipedia.org/wiki/Isolobal_principle

    In organometallic chemistry, the isolobal principle (more formally known as the isolobal analogy) is a strategy used to relate the structure of organic and inorganic molecular fragments in order to predict bonding properties of organometallic compounds. [1]

  5. Jemmis mno rules - Wikipedia

    en.wikipedia.org/wiki/Jemmis_mno_rules

    In chemistry, the Jemmis mno rules represent a unified rule for predicting and systematizing structures of compounds, usually clusters.The rules involve electron counting. They were formulated by E. D. Jemmis to explain the structures of condensed polyhedral boranes such as B 20 H 16, which are obtained by condensing polyhedral boranes by sharing a triangular face, an edge, a single vertex, or ...

  6. Inorganic chemistry - Wikipedia

    en.wikipedia.org/wiki/Inorganic_chemistry

    Inorganic compounds exhibit a range of bonding properties. Some are ionic compounds, consisting of very simple cations and anions joined by ionic bonding.Examples of salts (which are ionic compounds) are magnesium chloride MgCl 2, which consists of magnesium cations Mg 2+ and chloride anions Cl −; or sodium hydroxide NaOH, which consists of sodium cations Na + and hydroxide anions OH −.

  7. List of chemistry mnemonics - Wikipedia

    en.wikipedia.org/wiki/List_of_chemistry_mnemonics

    A mnemonic is a memory aid used to improve long-term memory and make the process of consolidation easier. Many chemistry aspects, rules, names of compounds, sequences of elements, their reactivity, etc., can be easily and efficiently memorized with the help of mnemonics.

  8. Inert-pair effect - Wikipedia

    en.wikipedia.org/wiki/Inert-pair_effect

    The inert-pair effect is the tendency of the two electrons in the outermost atomic s-orbital to remain unshared in compounds of post-transition metals.The term inert-pair effect is often used in relation to the increasing stability of oxidation states that are two less than the group valency for the heavier elements of groups 13, 14, 15 and 16.

  9. Kenneth Wade - Wikipedia

    en.wikipedia.org/wiki/Kenneth_Wade

    Kenneth Wade was born in Sleaford on 13 October 1932, the second son of Harry Kennington Wade and his wife, Anna Elizabeth Wade. He was educated at Carre's Grammar School, [2] and graduated from the University of Nottingham as the first PhD student (1954–1957) of Norman Greenwood, [3] [4] and Cornell University.