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The terms anode and cathode are not defined by the voltage polarity of electrodes, but are usually defined by the direction of current through the electrode. An anode usually is the electrode of a device through which conventional current (positive charge) flows into the device from an external circuit, while a cathode usually is the electrode through which conventional current flows out of ...
Aluminum sacrificial anodes (light colored rectangular bars) mounted on a steel jacket structure. Zinc sacrificial anode (rounded object) screwed to the underside of the hull of a small boat. Cathodic protection (CP; / k æ ˈ θ ɒ d ɪ k / ⓘ) is a technique used to control the corrosion of a metal surface by making it the cathode of an ...
The electropotential difference between the reactions at the two electrodes is the driving force for an accelerated attack on the anode metal, which dissolves into the electrolyte. This leads to the metal at the anode corroding more quickly than it otherwise would and corrosion at the cathode being inhibited.
The difference can be measured as a difference in voltage potential: the less noble metal is the one with a lower (that is, more negative) electrode potential than the nobler one, and will function as the anode (electron or anion attractor) within the electrolyte device functioning as described above (a galvanic cell).
In brief, corrosion is a chemical reaction occurring by an electrochemical mechanism (a redox reaction). [1] During corrosion of iron or steel there are two reactions, oxidation (equation 1), where electrons leave the metal (and the metal dissolves, i.e. actual loss of metal results) and reduction, where the electrons are used to convert oxygen and water to hydroxide ions (equation 2): [2]
In the copper half-cell, the copper ions plate onto the copper electrode (reduction), taking up electrons that leave the external conductor. Since the Cu ++ ions (cations) plate onto the copper electrode, the latter is called the cathode. Correspondingly the zinc electrode is the anode. The electrochemical reaction is
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