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Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula SiO 2, commonly found in nature as quartz. [5] [6] In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant families of materials, existing as a compound of several minerals and as a synthetic product.
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide).The atoms are linked in a continuous framework of SiO 4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical formula of SiO 2.
Silica gel is an amorphous and porous form of silicon dioxide (silica), consisting of an irregular tridimensional framework of alternating silicon and oxygen atoms with nanometer-scale voids and pores. The voids may contain water or some other liquids, or may be filled by gas or vacuum.
The general formula is (Si x O 3x) 2x−, where one or more silicon atoms can be replaced by other 4-coordinated atom(s). The silicon:oxygen ratio is 1:3. Double rings have the formula (Si 2x O 5x) 2x− or a 2:5 ratio. The Nickel–Strunz classification is 09.C. Possible ring sizes include:
Another reaction, sometimes used, is aluminothermal reduction of silicon dioxide, as follows: [73] 3 SiO 2 + 4 Al → 3 Si + 2 Al 2 O 3. Leaching powdered 96–97% pure silicon with water results in ~98.5% pure silicon, which is used in the chemical industry.
Structure of the orthosilicate anion SiO 4− 4. A silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula [SiO (4-2x)− 4−x] n, where 0 ≤ x < 2. The family includes orthosilicate SiO 4− 4 (x = 0), metasilicate SiO 2− 3 (x = 1), and pyrosilicate Si 2 O 6− 7 (x = 0.5 ...
Calcium silicate, also known as slag, is produced when molten iron is made from iron ore, silicon dioxide and calcium carbonate in a blast furnace. When this material is processed into a highly refined, re-purposed calcium silicate aggregate, it is used in the remediation of acid mine drainage (AMD) on active and passive mine sites. [13]
Unlike other silica polymorphs, the crystal structure of stishovite resembles that of rutile (TiO 2). The silicon in stishovite adopts an octahedral coordination geometry, being bound to six oxides. Similarly, the oxides are three-connected, unlike low-pressure forms of SiO 2. In most silicates, silicon is tetrahedral, being bound to four ...