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The equilibrium constant for a full redox reaction can be obtained from the standard redox potentials of the constituent half-reactions. At equilibrium the potential for the two half-reactions must be equal to each other and, of course, the number of electrons exchanged must be the same in the two half reactions. [32]
Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
The equilibrium constant of a chemical reaction is the value of its reaction quotient at chemical equilibrium, a state approached by a dynamic chemical system after sufficient time has elapsed at which its composition has no measurable tendency towards further change. For a given set of reaction conditions, the equilibrium constant is ...
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A stirred BZ reaction mixture showing changes in color over time. The discovery of the phenomenon is credited to Boris Belousov.In 1951, while trying to find the non-organic analog to the Krebs cycle, he noted that in a mix of potassium bromate, cerium(IV) sulfate, malonic acid, and citric acid in dilute sulfuric acid, the ratio of concentration of the cerium(IV) and cerium(III) ions ...
A Maucha diagram, or Maucha symbol, is a graphical representation of the major cations and anions in a chemical sample. R. Maucha [1] published the symbol in 1932. [2] Maucha ionic diagram. It is mainly used by biologists and chemists for quickly recognising samples by their chemical composition. [3] [4] The symbol is similar in concept to the ...
The diagram above illustrates the point that a precipitate that is not one of the main species in the solution equilibrium may be formed. At pH just below 5.5 the main species present in a 5 μM solution of Al 3+ are aluminium hydroxides Al(OH) 2+ , AlOH + 2 and Al 13 (OH) 7+ 32 , but on raising the pH Al(OH) 3 precipitates from the solution.
Chemical structures and reaction schemes should conform to the following: Images should be drawn with a molecule editor, never freehand; ACS settings should be used for both structures and reaction schemes. These settings are normally available as templates in chemical drawing programs. Use sans-serif fonts like Arial.