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Lesser amounts of other hydrated compounds also form: e.g. Fe(SCN) 3 and [Fe(SCN) 4] −. [19] Similarly, Co 2+ gives a blue complex with thiocyanate. [20] Both the iron and cobalt complexes can be extracted into organic solvents like diethyl ether or amyl alcohol. This allows the determination of these ions even in strongly coloured solutions.
Phenyl thiocyanate and phenyl isothiocyanate are isomers.. Organic thiocyanates are organic compounds containing the functional group RSCN. the organic group is attached to sulfur: R−S−C≡N has a S–C single bond and a C≡N triple bond.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Download as PDF; Printable version; ... OF 2, PdF 2, PdF 4, FSO 2 OOSO 2 F, POF 3, PF 5, ... sulfate – Fe 2 (SO 4) 3; Iron(III) thiocyanate – Fe(SCN) 3; Iron(II ...
Download as PDF; Printable version; ... Iron(III) sulfate: Fe 2 (SO 4) 3 ·H 2 O: 25.6: L ... PbC 4 H 4 O 6: 0.0025: Lead(II) thiocyanate: Pb(SCN) 2: 0.553: Lead(II ...
Thiocyanate complexes are not widely used commercially. Possibly the oldest application of thiocyanate complexes was the use of thiocyanate as a test for ferric ions in aqueous solution. [14] The reverse was also used: testing for the presence of thiocyanate by the addition of ferric salts. The 1:1 complex of thiocyanate and iron is deeply red.
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Mercury(II) thiocyanate (Hg(SCN) 2) is an inorganic chemical compound, the coordination complex of Hg 2+ and the thiocyanate anion. It is a white powder. It is a white powder. It will produce a large, winding "snake" when ignited, an effect known as the Pharaoh's serpent .