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Spectrochemistry is the application of spectroscopy in several fields of chemistry. It includes analysis of spectra in chemical terms, and use of spectra to derive the structure of chemical compounds, and also to qualitatively and quantitively analyze their presence in the sample.
A spectrochemical series is a list of ligands ordered by ligand "strength", and a list of metal ions based on oxidation number, group and element.For a metal ion, the ligands modify the difference in energy Δ between the d orbitals, called the ligand-field splitting parameter in ligand field theory, or the crystal-field splitting parameter in crystal field theory.
The reagent removes pairs of H atoms from organic molecules. The stoichiometry of its action is illustrated by the conversion of tetralin to naphthalene: . 2 C 6 Cl 2 (CN) 2 O 2 + C 10 H 12 → 2 C 6 Cl 2 (CN) 2 (OH) 2 + C 10 H 8
p-Xylene (para-xylene) is an aromatic hydrocarbon.It is one of the three isomers of dimethylbenzene known collectively as xylenes.The p-stands for para-, indicating that the two methyl groups in p-xylene occupy the diametrically opposite substituent positions 1 and 4.
Spectrochimica Acta Part B: Atomic Spectroscopy is a monthly peer-reviewed scientific journal covering spectroscopy.. The journal was established in 1939 as Spectrochimica Acta.
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Trifluoroacetic acid (TFA) is a synthetic organofluorine compound with the chemical formula CF 3 CO 2 H. It is a haloacetic acid, with all three of the acetyl group's hydrogen atoms replaced by fluorine atoms.
The elementary reaction responsible for water quantification in the Karl Fischer titration is oxidation of sulfur dioxide (SO 2) with iodine: . H 2 O + SO 2 + I 2 → SO 3 + 2 HI. This elementary reaction consumes exactly one molar equivalent of water vs. iodine.