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Supercritical hydrolysis is a method of converting all biomass polysaccharides as well the associated lignin into low molecular compounds by contacting with water alone under supercritical conditions. The supercritical water, acts as a solvent, a supplier of bond-breaking thermal energy, a heat transfer agent and as a source of hydrogen atoms.
Supercritical water oxidation (SCWO) is a process that occurs in water at temperatures and pressures above a mixture's thermodynamic critical point. Under these conditions water becomes a fluid with unique properties that can be used to advantage in the destruction of recalcitrant and hazardous wastes such as polychlorinated biphenyls (PCB) or ...
Superheated water, along with supercritical water, has been used to oxidise hazardous material in the wet oxidation process. Organic compounds are rapidly oxidised without the production of toxic materials sometimes produced by combustion. However, when the oxygen levels are lower, organic compounds can be quite stable in superheated water.
The SCWR operates at supercritical pressure. The reactor outlet coolant is supercritical water.Light water is used as a neutron moderator and coolant. Above the critical point, steam and liquid become the same density and are indistinguishable, eliminating the need for pressurizers and steam generators (), or jet/recirculation pumps, steam separators and dryers ().
Supercritical fluid, a substance at a temperature and pressure above its thermodynamic critical point: Supercritical carbon dioxide: Supercritical fluid chromatography, a form of liquid chromatography using supercritical carbon dioxide as the mobile phase; Supercritical water:
The dashed green line shows the anomalous behavior of water. For simplicity and clarity, the generic notion of critical point is best introduced by discussing a specific example, the vapor–liquid critical point. This was the first critical point to be discovered, and it is still the best known and most studied one.
Supercritical water exists at temperatures above 374 °C and pressures above 220 atmospheres. Diagram of a supercritical water-cooled nuclear reactor. A supercritical steam generator is a type of boiler that operates at supercritical pressure and temperature, frequently used in the production of electric power.
Supercritical hydrolysis is a chemical engineering process in which water in the supercritical state can be employed to achieve a variety of reactions within seconds. To cope with the extremely short times of reaction on an industrial scale, the process should be continuous .