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Atactic polypropylene has lower density, melting point and softening temperature than the crystalline types and is tacky and rubber-like at room temperature. It is a colorless, cloudy material and can be used between −15 and +120 °C. Atactic polypropylene is used as a sealant, as an insulating material for automobiles and as an additive to ...
In the mid-to-late-1950s, atactic polypropylene (APP) was a by-product of the synthesis of isotactic polypropylene (iPP) using first and early second generation Ziegler–Natta catalysts (Z-N catalysts), which typically produced about 10-15 wt% of APP.
In atactic macromolecules the substituents are placed randomly along the chain. The percentage of m diads is understood to be between 45 and 55% unless otherwise specified, but it could be any value other than 0 or 100% if that usage is clarified. [ 3 ]
ASTM D6222 / D6222M-16 Standard — Specification for Atactic Polypropylene (APP) Modified Bituminous Sheet Materials Using Polyester Reinforcements. [11] Type 1; Type 2; Grade G, surface coated granules; Grade S, smooth surface (uncoated) The Canadian Standards Association standards are: CSA A123.3 Asphalt Saturated Organic Roofing Felt
A polymer that lacks any regular arrangement in the position of its alkyl substituents (R) is called atactic. Both isotactic and syndiotactic polypropylene are crystalline, whereas atactic polypropylene, which can also be prepared with special Ziegler–Natta catalysts, is amorphous.
For example, atactic polypropylene is usually amorphous and transparent while syndiotactic polypropylene, which has crystallinity ~50%, is opaque. [30] Crystallinity also affects dyeing of polymers: crystalline polymers are more difficult to stain than amorphous ones because the dye molecules penetrate through amorphous regions with greater ease.
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