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In other words, zeta potential is the potential difference between the dispersion medium and the stationary layer of fluid attached to the dispersed particle. The zeta potential is caused by the net electrical charge contained within the region bounded by the slipping plane, and also depends on the location of that plane. Thus, it is widely ...
DLVO theory is a theory of colloidal dispersion stability in which zeta potential is used to explain that as two particles approach one another their ionic atmospheres begin to overlap and a repulsion force is developed. [1]
Usually zeta potential is used for estimating the degree of DL charge. A characteristic value of this electric potential in the DL is 25 mV with a maximum value around 100 mV (up to several volts on electrodes [22] [27]). The chemical composition of the sample at which the ζ-potential is 0 is called the point of zero charge or the iso-electric ...
According to Gauss’s law, a conductor at equilibrium carrying an applied current has no charge on its interior.Instead, the entirety of the charge of the conductor resides on the surface, and can be expressed by the equation: = where E is the electric field caused by the charge on the conductor and is the permittivity of the free space.
where ε r is the dielectric constant of the dispersion medium, ε 0 is the permittivity of free space (C 2 N −1 m −2), η is dynamic viscosity of the dispersion medium (Pa s), and ζ is zeta potential (i.e., the electrokinetic potential of the slipping plane in the double layer, units mV or V).
Phase-analysis light scattering (PALS) is a method for evaluating zeta potential, in which the rate of phase change of the interference between light scattered by the sample and the modulated reference beam is analyzed. This rate is compared with a mathematically generated sine wave predetermined by the modulator frequency. [4]
Zeta potential titration is a titration of heterogeneous systems, for example colloids and emulsions. Solids in such systems have very high surface area. This type of titration is used to study the zeta potential of these surfaces under different conditions. Details of zeta potential definition and measuring techniques can be found in the ...
The first step is to specify the electrostatic potential for ion j by means of Poisson's equation = ψ(r) is the total potential at a distance, r, from the central ion and ρ(r) is the averaged charge density of the surrounding cloud at that distance.